Ascent Petrochem Holdings Co., Limited

Knowledge

Material Safety Data Sheet (MSDS): Triethylene Glycol Diacrylate

Identification

Product Name: Triethylene Glycol Diacrylate
Synonyms: TEGDA, 2-Propenoic acid, 2,2’-[(2-oxybis(2,1-ethanediyloxy)]diethyl ester
CAS Number: 5969-32-2
Recommended Use: Used as a reactive diluent in UV-cured inks, coatings, adhesives, sealants, and resins
Supplier Information: Manufacturer and supplier details provided on packaging or request
Emergency Telephone Number: Available on product label or via local poison control centers

Hazard Identification

Classification: Eye irritant (Category 2A), Skin sensitizer (Category 1), Skin irritant (Category 2)
GHS Label Elements: Signal word: Warning. Exclamation mark pictogram present
Hazard Statements: Causes serious eye irritation. Causes skin irritation. May cause allergic skin reaction
Precautionary Statements: Avoid contact with eyes and skin. Wear protective gloves and eye protection. Wash hands thoroughly after handling. Use only outdoors or in well-ventilated areas
Potential Health Effects: Eyes: redness, pain, watering; Skin: irritation, rash, redness; Inhalation: irritation of respiratory tract, coughing, sore throat; Ingestion: abdominal pain, nausea, vomiting, possible chemical burns

Composition / Information on Ingredients

Chemical Name: Triethylene Glycol Diacrylate
CAS Number: 5969-32-2
Concentration: >97% by weight (industrial/commercial grade)
Impurities: Residual inhibitors (trace amounts), possible trace acrylic acid
Other Components: Stabilizers may be present to prevent polymerization during storage and transport

First Aid Measures

Inhalation: Move person to fresh air. Call for medical attention if symptoms persist. Give artificial respiration if breathing stops
Eye Contact: Rinse immediately with clean running water for at least 15 minutes. Remove contact lenses. Seek medical advice
Skin Contact: Remove contaminated clothing. Wash affected area thoroughly with soap and water. If irritation continues, seek medical care
Ingestion: Rinse mouth. Never induce vomiting. Drink water to dilute if conscious. Seek medical assistance immediately
Notes for Medical Professionals: Treat symptomatically. Monitor for delayed effects. Watch for allergic reactions or respiratory issues

Fire-Fighting Measures

Suitable Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Water may be ineffective but can cool containers
Specific Hazards: Vapors heavier than air; may travel and ignite at remote points. Container explosion risk from pressure buildup
Hazardous Combustion Products: Acrid smoke, carbon monoxide, carbon dioxide, low molecular weight compounds
Firefighter Protective Equipment: Self-contained breathing apparatus and full protective gear
Special Procedures: Contain runoff to prevent environmental contamination; cool exposed containers with water spray

Accidental Release Measures

Personal Precautions: Wear suitable chemical-resistant gloves, goggles, and protective clothing. Avoid breathing vapor or mist
Environmental Precautions: Prevent liquid from entering drains, sewers, or waterways; use barriers if needed
Cleanup Methods: Absorb on inert material such as sand or earth. Collect and place in containers for proper disposal. Flush residues with plenty of water after pickup
Spill Reporting: Notify environmental authorities if released in large quantities; follow local regulations

Handling and Storage

Precautions for Safe Handling: Prevent skin and eye contact. Do not inhale vapors. Use within well-ventilated areas. Avoid sources of ignition
Storage Requirements: Store tightly closed in a dry, cool, and well-ventilated space. Keep away from heat, flames, oxidizing agents, and direct sunlight. Use inert gas blanket for long-term storage to prevent polymerization
Incompatible Materials: Strong acids, strong bases, oxidizers, free radical initiators
Safe Transfer Methods: Ground and bond equipment; use static-free practices

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established OSHA PEL or ACGIH TLV. Minimize exposure. Maintain concentrations below recommended threshold by engineering controls
Engineering Controls: Use fume hoods, chemical exhaust ventilation, or local exhaust where vapor may be generated
Personal Protective Equipment: Gloves (nitrile or neoprene), splash-proof chemical goggles, lab coats, closed footwear. Respirator use may be necessary in poorly ventilated spaces or for large spills
Hygiene Measures: Wash hands after handling. Remove contaminated clothing. Do not eat, drink, or smoke near product
Environmental Controls: Prevent discharge to soil, water, or air outside of permitted facilities

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Mild, acrylate odor
pH: Not determined (practically neutral)
Melting Point: -38°C
Boiling Point: 284°C (estimated, decomposes)
Flash Point: 144°C (closed cup)
Evaporation Rate: Slower than butyl acetate
Flammability: Combustible under certain conditions
Vapor Pressure: <0.01 mmHg at 20°C
Vapor Density: Greater than air
Solubility: Insoluble in water, soluble in most organic solvents
Partition Coefficient (log Kow): Estimated at 2.2
Viscosity: 12-16 mPa·s at 25°C
Density: 1.1-1.12 g/cm³ at 20°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions. Inhibited to prevent unwanted polymerization
Hazardous Reactions: Can polymerize violently with heat, light, or contamination by peroxides, acids, or bases
Conditions to Avoid: Heating, exposure to sunlight, contamination by free radical initiators
Incompatible Materials: Free radical initiators, strong oxidizing agents, strong acids/bases
Hazardous Decomposition Products: Acrylic acid, oxides of carbon, smoke, acrid fumes

Toxicological Information

Acute Toxicity: Low oral and dermal toxicity; may cause irritation at contact sites
Skin Sensitization: Skin contact can trigger allergic reactions in sensitive individuals; repeated or prolonged exposure increases risk
Eye Irritation: Direct exposure causes severe irritation, redness, pain
Respiratory Effects: Mist or vapor inhalation can irritate nose, throat, and lungs
Chronic Exposure: Possible dermatitis, skin dryness, or rash. No comprehensive animal carcinogenicity data
Other Effects: No evidence of reproductive toxicity or mutagenic effects based on available studies
Medical Conditions Aggravated: Pre-existing skin or respiratory conditions

Ecological Information

Environmental Toxicity: Harmful to aquatic life with long-lasting effects. Toxic to fish and invertebrates at elevated concentrations
Mobility: Low volatility, does not easily vaporize. Tends to bind to sediments
Persistence and Degradability: Not readily biodegradable; remains for extended periods in soil or water. Shows potential for bioaccumulation
Bioaccumulation Potential: Likelihood of accumulation in aquatic organisms over time
Other Information: Prevent entry to drains, sewers, waterways, or soil. Local regulations may classify as hazardous to the environment

Disposal Considerations

Waste Disposal: Treat as hazardous waste under federal/state/local regulations for chemical wastes
Contaminated Packaging: Empty containers retain product residue and vapors; treat with same caution as full containers. Clean thoroughly and recondition or dispose through licensed facility
Recommended Disposal Methods: Incineration in approved facility. Do not landfill unless permitted
Special Instructions: Avoid disposal to surface or ground water. Comply with local environmental requirements
Waste Codes: Consult national and local authorities to determine proper classification and handling

Transport Information

UN Number: Not regulated as a dangerous good for most transport modes. Check current ADR, IMDG, IATA guidelines
Transport Hazard Class: Not classified as hazardous under current transport laws, but large volumes may require safety precautions and proper labeling
Packing Group: Not assigned
Environmental Hazards: May be subject to marine pollutant regulations depending on jurisdiction
Special Transport Precautions: Prevent leakage, secure containers upright, keep away from incompatible cargo. Mark packaging with appropriate hazard warnings

Regulatory Information

US Regulations: Not listed as a hazardous substance under SARA Title III or CERCLA. Product appears on TSCA inventory
European Regulations: Listed in EINECS/ELINCS. Classified according to REACH for skin/eye sensitization
Labeling Requirements: Product label must state hazard class and precaution details consistent with current GHS/CLP guidelines
Workplace Requirements: Comply with OSHA chemical hygiene requirements or EU employer obligations on chemical safety
Other International Regulations: Comply with workplace exposure and environmental release controls established by national and local agencies