Product Name: Tetrahydrofurfuryl Acrylate
Chemical Formula: C9H12O3
CAS Number: 2399-48-2
Synonyms: 2-(Acryloyloxy)methyltetrahydrofuran
Recommended Uses: Used in resins, coatings, adhesives, inks, and other polymer applications
Supplier: Listed supplier information with emergency contact details
GHS Classification: Skin Irritant (Category 2), Eye Irritant (Category 2A), Skin Sensitizer (Category 1), Specific Target Organ Toxicity - Single Exposure (Category 3)
Signal Word: Warning
Hazard Statements: Causes skin irritation; Causes serious eye irritation; May cause an allergic skin reaction; May cause respiratory irritation
Pictograms: Exclamation mark, Health hazard
Precautionary Statements: Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Use only outside or in a well-ventilated area.
Chemical Name: Tetrahydrofurfuryl Acrylate
CAS Number: 2399-48-2
Concentration: 95–100%
Impurities: Traces of inhibitors (for stabilization); possible traces of acrylic acid
Other Information: No hazardous components present above cut-off values
Inhalation: Move to fresh air. Seek medical attention if symptoms develop.
Skin Contact: Remove contaminated clothing. Wash affected area with plenty of soap and water. Seek medical advice for persistent irritation.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek immediate medical care.
Ingestion: Rinse mouth. Do not induce vomiting. Seek immediate medical attention.
Most Important Symptoms: Burning sensation, redness, rash, coughing, difficulty breathing
Notes to Physician: Treat symptomatically and provide supportive care
Suitable Extinguishing Media: Dry chemical, foam, CO2, water spray (avoid strong water jet)
Specific Hazards: Vapors may form explosive mixtures with air. Can produce irritating and toxic fumes under fire conditions (carbon oxides, acrid smoke).
Protective Equipment for Firefighters: Self-contained breathing apparatus and full protective clothing.
Precautions: Keep containers cool with water spray to avoid pressure build-up and rupture.
Special Procedures: Evacuate area and fight fire from a safe distance. Use water to cool nearby containers and surfaces.
Personal Precautions: Wear suitable protective equipment including gloves, goggles, and respirator when necessary. Avoid contact with skin, eyes, and clothing. Ensure adequate ventilation.
Environmental Precautions: Prevent product from entering drains, waterways, or soil.
Containment: Stop leak if safe to do so. Contain spill with inert absorbent materials like sand or earth.
Clean Up: Collect product and absorbent material into properly labeled containers for disposal. Clean contaminated surfaces thoroughly.
Emergency Procedures: Isolate area. Keep unauthorized personnel away.
Handling: Use only in a well-ventilated area. Avoid breathing vapor or mist. Wear suitable protective gear. Avoid skin and eye contact. Wash hands before breaks and after work.
Storage: Keep containers tightly closed and in a cool, dry, well-ventilated place, away from direct sunlight and heat sources. Store away from oxidizing agents, acids, and bases. Protect from physical damage.
Incompatibilities: Strong acids, bases, oxidizing agents, and reducing agents.
Special Storage Instructions: Product contains inhibitor to prevent polymerization; keep container closed to maintain effectiveness.
Occupational Exposure Limit: Not specifically established for tetrahydrofurfuryl acrylate. Use appropriate limits for nuisance particulates.
Engineering Controls: Local exhaust ventilation or general dilution ventilation.
Personal Protective Equipment (PPE): Chemical-resistant gloves (nitrile), safety goggles or face shield, impervious clothing, suitable respiratory protection if good ventilation is lacking.
Hygiene Measures: Avoid contact with skin, eyes, and clothing. Do not eat, drink, or smoke during use.
Appearance: Clear, colorless to pale yellow liquid
Odor: Slight acrylate odor
pH: Not applicable
Melting Point/Freezing Point: -20°C
Boiling Point: 215°C
Flash Point: 98°C (closed cup)
Evaporation Rate: Not available
Flammability: Combustible
Vapor Pressure: 0.06 mmHg @ 20°C
Vapor Density: >1 (Air = 1)
Solubility: Slightly soluble in water; soluble in most organic solvents
Partition Coefficient (n-octanol/water): 1.1
Viscosity: 10–25 mPa.s @ 25°C
Density: 1.11 g/cm³
Chemical Stability: Stable under recommended storage conditions. Inhibitor added to prevent polymerization.
Reactivity: Avoid heat, sunlight, and incompatible materials.
Hazardous Reactions: Polymerizes exothermically under strong heating or in presence of initiators, peroxides, or absence of inhibitor.
Incompatible Materials: Strong acids, bases, oxidizers, reducing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke.
Acute Toxicity: Oral LD50 (rat) 4,500 mg/kg; Dermal LD50 (rabbit) >2,000 mg/kg. Irritant to skin and eyes in animal studies.
Skin Corrosion/Irritation: Causes irritation, redness, and discomfort
Serious Eye Damage/Irritation: Causes moderate to severe irritation
Respiratory or Skin Sensitization: Skin sensitizer; repeated exposure may cause allergic reactions
Germ Cell Mutagenicity: No data
Carcinogenicity: Not classified
Reproductive Toxicity: Not classified
STOT - Single/Repeated Exposure: May cause respiratory irritation with high vapor concentrations
Aspiration Hazard: Not known
Additional Data: Exposure may aggravate pre-existing dermatitis or respiratory conditions
Ecotoxicity: Toxic to aquatic organisms with long lasting effects (based on acrylate monomer group data).
Persistence and Degradability: Not readily biodegradable; risk of bioaccumulation is low.
Bioaccumulative Potential: Log Pow 1.1; bioaccumulation potential is limited.
Mobility in Soil: Mobile in the environment and may leach through soil.
Other Adverse Effects: No specific data; avoid release to the environment.
Waste Disposal Methods: Incinerate in a licensed facility; observe local, state, and federal laws.
Packaging Disposal: Empty containers may retain hazardous residue. Do not reuse. Dispose of as hazardous waste.
Special Precautions: Avoid discharge into waterways or sewer systems.
Recommended Measures: Consult with local hazardous waste authorities and follow proper labeling and transport rules for hazardous waste.
UN Number: 3082 (if classified as environmentally hazardous substance, liquid, n.o.s.)
UN Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains Tetrahydrofurfuryl Acrylate)
Transport Hazard Class: 9 (Miscellaneous Dangerous Substances)
Packing Group: III
Marine Pollutant: Yes
Special Precautions for User: Ensure packaging is intact and labeled. Avoid exposure to static discharge.
Transport in Bulk: Not regulated under Annex II of MARPOL
Land Transport (ADR/RID): Classified as dangerous goods; follow local transport regulations.
US Regulations: Listed on TSCA inventory. OSHA Hazard Communication Standard: hazardous chemical.
EU Regulations: Classified according to Regulation (EC) No 1272/2008 (CLP/GHS); REACH registered.
Other International Inventories: Listed on relevant chemical inventories (Canada DSL, Australia AICS, Japan ENCS, China IECSC, Korea KECI, Philippines PICCS).
SARA 313: Not subject to reporting requirements
Label Elements: GHS pictograms and hazard statements legally required.
Restrictions: Use in industrial setting only; keep away from food and feedstuffs.
