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N-Butyl Acrylate: Past, Present, and What’s Next

Historical Development

N-Butyl Acrylate has roots digging back to efforts by chemists in the early 1900s who experimented with acrylate esters, looking for better building blocks for plastics and coatings. The boom of the plastics industry in the 1930s and 1940s drove real production, especially as synthetics elbowed out natural resins in paints and adhesives. Over the decades, refining catalytic processes allowed factories to churn out higher purity N-Butyl Acrylate. I remember reading about how, by the 1970s, industries in America, Europe, and Japan scaled up production rapidly, mostly due to growing demand for acrylate-based emulsion polymers used in paint and textiles.

Product Overview

N-Butyl Acrylate stands out as a key player in the realm of acrylate esters. Its chemical backbone—a butyl group hooked up to acrylic acid’s carbonyl—translates into certain practical perks, especially for manufacturers needing flexible, light-stable, and weather-resistant materials. In paint formulations, the compound helps balance toughness and flexibility. For adhesives, it sticks well, literally and figuratively, due to its low glass transition temperature which keeps finished products pliable. My own hands-on encounters with basic acrylics show that N-Butyl Acrylate is a keen fit wherever polymers demand a mix of softness and resilience.

Physical & Chemical Properties

At room temperature, N-Butyl Acrylate is a clear, colorless liquid. Its fruity, sharp odor lingers in the air—not pleasant, but recognizable if you’ve spent any time near chemical drums. Its boiling point looms around 146°C, while it flashes at just 39°C, so it needs careful storage. The density floats close to 0.89 g/cm³. The molecule dissolves in most organic solvents like alcohol, ether, and acetone, but water only grudgingly accepts it. In terms of reactivity, the double bond attached to the acrylic acid part invites polymerization, sometimes more swiftly than operators expect. Those familiar with its quirks respect the ease with which it forms polymers by free radical initiation, especially when exposed to heat, light, or peroxides.

Technical Specifications & Labeling

Drums and tankers of N-Butyl Acrylate rarely leave a producer’s facility without detailed labeling. Besides the name and purity (often above 99%), labels usually show batch numbers, shelf life, stabilization agent type, and hazard warnings about flammability and toxicity. Safety Data Sheets spell things out further—N-Butyl Acrylate lands in hazard class 3 for flammable liquids and bears GHS symbols for acute toxicity and skin irritation. I’ve often seen manufacturers reference ASTM and ISO standards for composition and stability checks before shipments head out.

Preparation Method

Making N-Butyl Acrylate on an industrial scale means bringing acrylic acid and n-butanol together in the presence of an acid catalyst, like sulfuric acid or p-toluenesulfonic acid. Under heat, this reaction forms water, so factories use distillation to separate product and drive the process forward. Modern plants rely on continuous processes with closed reactors, which keep workers safer from fumes and save energy. Catalyst recovery and waste stream treatment have become essential, partly due to stricter regulatory oversight of chemical manufacturing. I watched an old training video showing early batch processes—losses used to be high before automation tightened every step.

Chemical Reactions & Modifications

The backbone of N-Butyl Acrylate invites a host of downstream chemistry. Free radical polymerization, coaxed by initiators like benzoyl peroxide or AIBN, leads to acrylate homopolymers or co-polymers with styrene, methyl methacrylate, or vinyl acetate. Manufacturers often tweak the process to boost molecular weight or fine-tune the hardness of the end product. N-Butyl Acrylate can also react with isocyanates to produce urethane-acrylate systems—useful for tough coatings. In advanced labs, chemical modification turns into a race to insert new functional groups, graft copolymers, or boost weathering resistance, a constant drumbeat in industrial R&D.

Synonyms & Product Names

I’ve come across N-Butyl Acrylate listed under several nicknames: butyl acrylate, acrylate butyl ester, and even “BA” in shop talk. On labeling from various suppliers and in MSDS sheets, you’ll spot CAS numbers (141-32-2) as the surest identifier. Brand names differ, with each chemical giant touting proprietary versions meeting their own in-house specs—often you see “n-Butyl Acrylate Monomer” or regional notations like “BA-N.” Tracing these synonyms matters when navigating global supply chains or comparing regulatory filings across major markets.

Safety & Operational Standards

Working with N-Butyl Acrylate isn’t as straightforward as opening a can of paint. Its vapors can irritate the eyes, skin, and respiratory tract. Long exposure at work has led to cases of dermatitis or headaches. Leakage risks fire, due to its low flash point. Factories lean hard on explosion-proof ventilation and emergency protocols—static electricity near open containers counts as bad news. I’ve learned that strict PPE rules (gloves, goggles, organic vapor masks) keep incidents low, but managerial vigilance makes the biggest difference. OSHA sets workplace limits, and European REACH rules demand ever-tightening emission caps. Proper storage—cool, dry, and away from oxidizers—prevents drama on the shop floor.

Application Area

Hardly a day goes by without brushing up against products that rely on N-Butyl Acrylate in their makeup. Water-based paints, pressure-sensitive adhesives, sealants, textile finishes, and even glossy paper coatings often trace their performance back to this chemical. The push for low-VOC “green” coatings still leans heavily on acrylate chemistry, thanks to how well N-Butyl Acrylate balances flexibility and weather resistance. Manufacturers in every region chase customer demand for tougher, stickier, or more heatproof products, leading to endless tweaks in acrylic copolymer recipes. In my talks with industrial chemists, it’s clear that finding substitutes is tough; few materials check as many boxes without major tradeoffs.

Research & Development

Research around N-Butyl Acrylate races to squeeze more value from every ton and cut down on environmental harm. Companies invest heavily in catalysts that streamline synthesis, reduce waste, and recycle reaction byproducts. In the academic world, teams focus on novel copolymers, self-healing coatings, or nanostructured films with targeted properties. Analytical methods grow more sophisticated—NMR, chromatography, and advanced rheology pull new insights about how polymer architecture links to real-world durability. On the sustainability front, a wave of R&D aims at using bio-based feedstocks in place of fossil acrylic acid, although economic hurdles still keep these options niche. The future will likely see more cross-pollination between green chemistry and industrial economics as regulatory and consumer pressures continue to mount.

Toxicity Research

Questions about N-Butyl Acrylate’s health effects kicked up around the time its use spread in the 1940s and 1950s. Acute exposure can sting skin and eyes, cause headaches and nausea, and, at high enough concentrations, depress the central nervous system. Long-term studies in animals point to irritation and weight loss at repeated high exposures, but carcinogenicity evidence remains pretty limited according to the EPA and ECHA readings. I remember combing through regulatory guidance to see occupational exposure limits drop over the years. Until green chemistry breakthroughs really take hold, careful containment and monitoring will matter just as much as the base science when handling this stuff.

Future Prospects

Demand for N-Butyl Acrylate shows no signs of slowing, though the market faces turbulence from shifts in raw material pricing and tightening environmental targets. As regulations push for safer, lower-emission products, chemical plants and R&D labs press farther into cleaner production methods, higher-yield processes, and safer formulations. Alternative acrylates and bio-based options lurk just over the horizon, but don’t expect the world to turn away from N-Butyl Acrylate overnight—it’s deeply woven into the fabric of industrial chemistry. From paints that last decades to adhesives in high-performance electronics, the drive to balance utility, safety, and footprint will chart the path ahead. Every round of innovation, every tweak in process, carries the possibility of turning this old standby into something even more useful—and less burdensome on people and planet alike.



What is N-Butyl Acrylate used for?

Everyday Uses People Don’t Think About

N-Butyl acrylate sounds like the sort of thing you’d find in a scary warning label, but most folks interact with its handiwork without even knowing it. Cabinets, painted walls, those glossy magazine covers—many came out just right because this one chemical played a part. Manufacturers use it to make plastics and resins that end up in coatings, adhesives, paints, and even fabric finishes. Some people may know how paint holds up well in the rain or how flooring doesn’t scuff up right away. N-Butyl acrylate helps deliver that durability.

The Role in Paints and Coatings

In practical life, people want walls and fences that can take a beating from sun and water. A fresh coat of paint stays on longer and looks sharper because n-butyl acrylate gives it that extra bond and flexibility. I remember painting an old garden fence; years later, every board still looked decent because of the weather-resistant paint. That’s often thanks to this chemical making the paint a bit springy, not cracking as wood expands and contracts.

Keeping Stuff Together: Adhesives and Glue

Every craftsman or DIY fan has reached for a bottle of glue, stuck two things together, and trusted that bond. N-butyl acrylate crops up here, too. The sticky layers keeping your shoes from splitting or your kid’s latest project in one piece rely on acrylic adhesives partly made from this substance. These glues take on tough jobs, resisting water and not turning brittle as time passes.

Textiles and Flexible Plastics

People expect fabrics to stretch, recover, and endure more washes than before. N-butyl acrylate makes fibers stretchier and more comfortable against skin. Think of sportswear that moves with each step, or banners that don’t rip apart in sudden wind. Polymer blends using this chemical find their way into dozens of soft, bendable products seen every day.

Environmental and Health Concerns

Every good thing carries its risks. N-butyl acrylate, like many industrial materials, turns tough behind the factory gates. Makers wear gloves and masks because fumes can irritate the skin and lungs. Regulators worry about emissions and waste, especially if the chemical spills into rivers or soil. Communities living near production plants sometimes worry about air quality and long-term exposure. Recent research highlights the potential hazards to aquatic life, and agencies such as the EPA and OSHA keep a close eye on how facilities store and use it.

Paths Toward Safer Use

Plenty of smart folks work on safer alternatives and smaller footprints. Water-based paints and adhesives cut down on harsh solvents. Companies invest in closed-loop systems to keep emissions in check and spend money upgrading old equipment. Training workers to spot leaks or handle emergencies gives everyone an extra layer of defense. Open communication with nearby neighborhoods builds trust, so people can feel confident that industry takes responsibility and doesn’t just chase profits at any cost.

A Chemical We Don’t See, Yet Depend On

N-butyl acrylate holds a strange position. Most consumers never hear its name, yet it keeps daily comforts ticking along. Its story spotlights how chemistry shapes modern life, often behind the scenes. People value longer-lasting paint, stronger glue, and comfy fabrics— and keeping these benefits while trimming down risks remains a shared goal for workers and neighbors alike.

What are the safety precautions for handling N-Butyl Acrylate?

Understanding the Risks Firsthand

N-Butyl Acrylate runs into the lives of folks who work with paints, coatings, adhesives, and plastics. It’s a chemical that doesn’t mess around if you slip up. I’ve seen people underestimate the fumes and regret it fast—headaches, watery eyes, and rough skin are common complaints in shops that skimp on safety. Breathing in those vapors or splashing some on bare skin can turn an ordinary shift into a trip to the clinic.

Personal Protective Gear: Not Optional

Anyone handling this stuff gets to know bulky gear fast. Gloves should be chemical-resistant—nitrile or butyl rubber tend to hold up well against the liquid. Cotton or latex gloves just won’t cut it. A comfortable, full-coverage lab coat and protective goggles keep splashes and vapors from finding skin or eyes. In places with poor airflow, don’t count on a basic dust mask. It pays to suit up with a proper respirator, one rated for organic vapors.

Good Ventilation Means Fewer Worries

Opening a window won’t pull out these fumes. Anyone working with N-Butyl Acrylate needs proper exhaust systems or fume hoods that send vapors straight outside. A room fan just pushes the problem around. Air monitoring equipment doesn’t just sit in a corner for show—if those alarms go off, it signals real trouble for your lungs and nervous system.

Safe Handling: Care in Every Step

N-Butyl Acrylate doesn’t mix kindly with heat or sparks. Static can light up vapors, so everyone in the lab or production floor should leave lighters and cell phones outside. Pouring and transferring gets tricky—grounding containers before moving the liquid helps prevent static build-up. Spills demand speed and caution. I’ve learned that clay-based absorbents and non-sparking tools keep small leaks manageable, but large spills often mean calling in the professionals.

Smart Storage: Preventing Trouble Ahead

This chemical prefers cool, dry, and well-ventilated storage areas. Keeping it in tightly sealed, labeled containers, away from acids, bases, and oxidizers, drops the risk of unexpected reactions. The storage zone should sit far from open flames, direct sunlight, and sources of heat—N-Butyl Acrylate vapor is heavier than air and likes to settle low, so leaks can collect around the floor if ignored.

Immediate Action for Exposure

Accidents still happen, even with every safeguard in place. If the chemical touches skin, head straight to the wash station and rinse with water for at least fifteen minutes—no shortcuts. For eye contact, keep the eyelids open and flush with water, then get to a doctor. Inhaling too much vapor can cause serious symptoms in minutes; those affected need fresh air and medical help without delay. Quick action keeps small mistakes from becoming dangerous emergencies.

Building a Culture of Safety

Training does more than cover the basics. Regular drills and refresher courses mean each worker knows where to find the nearest exit, how to sound the alarm, and who to call in a pinch. Spreading awareness about the hidden dangers in daily routines builds habits that save lives. For managers and workers, keeping safety data sheets handy for review isn’t just box-ticking—it puts lives and livelihoods ahead of shortcuts.

What is the chemical formula and CAS number of N-Butyl Acrylate?

Understanding the Basics of N-Butyl Acrylate

N-Butyl acrylate has shaped plenty of industries, especially where strong, flexible coatings matter. Its chemical formula reads as C7H12O2 and the CAS number is 141-32-2. The details may sound dry at first glance, but for those dealing with paints, adhesives, and even textiles, getting familiar with these numbers can save a lot of effort—both in safety and product quality.

Why These Chemical Details Aren’t Just Trivia

For folks in manufacturing or even for anyone reading labels as part of workplace safety, knowing the precise identifier like the CAS number (141-32-2) means they’re dealing with the real thing. I’ve seen cases where confusion about chemical names led to mistakes in handling, storage, and legal compliance. Safety Data Sheets rely on that CAS number, so there’s no room for guesswork. The formula C7H12O2 doesn’t just help chemists; it gives everyone in the supply chain a direct way to check if what’s in the drum matches what’s in the spec sheet.

N-Butyl acrylate gives off a strong, fruity odor and can irritate the skin or eyes. I once watched somebody overlook this detail in a small furniture shop. A little spill led to a bigger headache than anyone expected, and it all traced back to a lack of awareness about its basic properties. Proper labels and clear knowledge of its formula help stop those kinds of accidents before they start.

Impact on the Workplace and the Environment

Most people don’t think twice about the raw materials in their everyday items—paints, glues, floor polish. But for every batch, workers and managers unite over these small but vital details. For years, my work in warehouse logistics taught me that mix-ups happen when documentation slackens. Some may shrug off chemical names as paperwork, but I witnessed the procedures change dramatically for the better once everyone keyed into the chemical’s formula and CAS number.

Regulations focus not just on the presence of these chemicals, but also on their management. In the European Union, regulations like REACH keep strict tabs. These rules use unique identifiers like the CAS number to track chemicals from the port to processing to shelf. In practice, supply chain traceability becomes possible only because every drum, bottle, or tank can be linked back to a globally-recognized number.

Staying Safe and Moving Forward

Goggles, gloves, and proper ventilation all start to make sense—not as overkill, but as standard because the risks are well-understood. Without a grasp of what C7H12O2 means, people face unnecessary risks. In regions where education on chemical safety gets overlooked, organizations focused on worker health have demanded clearer labeling and regular training based around real-world scenarios—no jargon, just basics.

Solutions come from good habits. Double-check labels, refer to the CAS number in all purchase and usage documents, and never hesitate to ask questions if the paperwork doesn’t match the drum. It’s not about policing each other, but building a routine where safety and product quality grow from shared attention to these details. Good training programs can turn basic chemical awareness from a checklist item into part of the company’s rhythm.

Final Thoughts on Everyday Chemistry

Knowing the formula C7H12O2 and the CAS number 141-32-2 isn’t just for the lab. It matters in real day-to-day decisions on the floor, in logistics, and at every point where people interact with products that drive modern life. The more familiar we become with these details, the safer and more reliable our workplaces and products become.

How should N-Butyl Acrylate be stored?

A Common Chemical with Big Risks

N-Butyl Acrylate shows up everywhere from adhesives to paints to coatings on everyday objects. It smells sharp and it stings when touched. The real danger comes from how reactive it is. This isn’t the kind of compound you leave in a hot warehouse corner or stash in a closet. Over the years, I’ve watched workplaces face headaches that could have been avoided with more respect for proper storage.

Heat and Light Are Not Friends Here

N-Butyl Acrylate has a low flash point around 27°C (80°F), so even a summer day can make it risky. It doesn’t take much for it to release flammable vapors. This isn’t hypothetical: fires have broken out before in facilities where containers sat near heat ducts or in sunlight.

To guard against this, use cool, ventilated spaces away from any source of ignition. As a rule, keep the containers sealed tight and never near open flames, sparks, or electrical equipment that can spark. OSHA and the National Fire Protection Association recommend storing N-Butyl Acrylate in flammable liquids cabinets rated for proper vapor containment. Sprinklers and fire extinguishers nearby aren’t just bells-and-whistles; they’re basic precautions.

Avoiding Polymerization: It’s Easier Than It Sounds

The biggest problem with N-Butyl Acrylate is runaway polymerization. Left unchecked, the liquid turns solid fast, releasing heat and pressure. The key is to buy stabilized product that contains enough inhibitor (usually about 10-20 ppm of MEHQ — methyl ether hydroquinone). When I worked in manufacturing, I saw stabilizer levels tested monthly, which helped us catch issues before they became emergencies.

Once stabilizer runs low, heat and impurities begin to speed up the process. Poor housekeeping — like using dirty containers or letting the chemical mix with acids or peroxides — brings extra risks, as even trace amounts can trigger messy reactions. Regular checks matter. Real-life cases show that spending a few minutes with a test kit saves thousands in cleanup and costly downtime.

Containers and Labeling Are Not Trivial Details

Use drums or totes made from stainless steel or special plastics (HDPE or PP), since ordinary metal corrodes or reacts. Double-check that every container stays labeled with both the substance name and hazard warnings. I worked at a site where relabeling was ignored “just for a few weeks,” and that led to a misidentification that almost landed someone in the ER. Safety Data Sheets (SDS) taped close by help staff double-check guidelines for handling and spills.

Plan for Spills and Leaks — Don’t Improvise

Facilities that succeed treat spill control as a daily practice, not a theoretical drill. N-Butyl Acrylate vapors move quickly and are heavier than air. Even a small spill can pool under doors or fill a low corner. I’ve seen foam-based fire suppression stop minor accidents from turning worse. Absorbent pads, neutralizers, and working exhaust fans should stay within arm’s reach of storage areas.

Training and Checks: The Real Game Changers

Staff turnover in warehouses is high, but training can’t fall between the cracks. Refreshers on proper storage, quick chemistry of the risks, and hands-on spill response pay for themselves in lives and dollars. Management that runs regular surprise audits get fewer close calls. People pay closer attention when they know checks are coming.

Managing N-Butyl Acrylate is about building strong habits. Store it cool, label it clearly, know your spill drill, and keep stabilization top-of-mind. Real-world disasters come from small mistakes. A bit of thought today saves a lot of trouble tomorrow.

What are the main physical and chemical properties of N-Butyl Acrylate?

Getting to Know N-Butyl Acrylate

N-Butyl acrylate, commonly called butyl acrylate, turns up in a lot of familiar products. Paints, adhesives, coatings, and sealants often depend on the flexibility and durability this chemical delivers. I’ve spent a few years in a lab that formulated wood coatings, and butyl acrylate always stood out as a go-to when we needed blends that stayed strong under heat and resisted brittleness. To understand its value, you have to dig into its properties, both physical and chemical.

Physical Features that Matter

This liquid tends to show a colorless, sometimes slightly yellow hue. It gives off a very recognizable, fruity odor—think something between sharp apples and markers—which any technician picking up a fresh drum can’t ignore. Its boiling point is about 145°C, so it handles moderate heating, but care is needed under open flames or high temperatures at a worksite. I remember spilling a bit during a summer shipment and watching it evaporate quickly; that comes from its volatility, reflected in a vapor pressure that isn’t as high as acetone or ethyl acetate, but enough to call for good ventilation.

Density clocks in at around 0.89 g/cm³, lighter than water, which means spills float on surfaces instead of sinking. Viscosity remains low—usually under 1 centipoise at room temperature—much thinner than vegetable oil and closer to alcohol. That helps it blend easily with other liquids during manufacturing, preventing chunks or unmixed streaks in the end product.

Chemical Behavior and Reactivity

Butyl acrylate acts like most acrylates, meaning it loves to react with itself in chain reactions, forming strong polymers. The molecule carries a double bond at the acrylate group, making it highly reactive in the presence of free radicals and heat. This trait is bread and butter for the paint and plastics world; that double bond opens up, linking with thousands of neighbors to build the backbone of tough, flexible films. Without that reactivity, all those chip-resistant coatings on home décor or protective sheens on your car wouldn’t last.

The compound dissolves well in most organic solvents—esters, alcohols, ketones—but barely mixes with water. If you try blending it with water, it forms a thin film that floats on top. Years ago, our QC team ran extensive mixing experiments; unless emulsifiers joined the party, butyl acrylate stubbornly separated every time. This resistance to water often gets cited as an advantage in outdoor coatings because moisture doesn’t break down the polymer chain as quickly.

Practical Hazards and Safe Storage

Butyl acrylate brings a low flash point, sitting around 39°C. Storing it near heat sources or open flames isn’t safe. In my own work, warehouses kept it far from sunlight and spark sources, with strict monitoring for leaks. Prolonged inhalation can cause headaches and irritation, so personal protective equipment always enters the scene, not just for lab workers but also for staff during large-scale applications. Over longer exposure, skin contact can lead to redness or even mild burns, which is why safety measures aren’t just red tape; they protect staff health and prevent environmental incidents.

Moving Forward Safely

Each facility that handles butyl acrylate benefits from focused protocols. Factories and labs often use inert gas blankets to stop accidental polymerization, and regular drum rotation keeps the chemical from getting too warm. By combining basic chemistry knowledge with workplace vigilance, manufacturers get the durable, attractive surfaces customers expect—without extra risk along the way.

N-Butyl Acrylate