Ascent Petrochem Holdings Co., Limited

Knowledge

Material Safety Data Sheet (MSDS): Lauryl Acrylate

1. Identification

Product Name: Lauryl Acrylate
Chemical Formula: C15H28O2
CAS Number: 2156-97-0
Synonyms: Dodecyl acrylate, Acrylate lauryl ester
Recommended Use: Monomer for polymerization, chemical manufacturing
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2. Hazard Identification

Classification: Flammable liquid (Category 3), Skin irritation (Category 2), Eye irritation (Category 2A), Skin sensitizer (Category 1), Hazardous to the aquatic environment – acute and chronic (Category 2)
Signal Word: Warning
Hazard Statements: Combustible liquid, causes skin and eye irritation, may cause an allergic skin reaction, toxic to aquatic life with long lasting effects
Pictograms: Exclamation mark, flame, environment
Precautionary Statements: Avoid breathing vapors, use personal protective equipment, wash hands after handling, avoid release to environment

3. Composition / Information on Ingredients

Chemical Name: Lauryl Acrylate
CAS Number: 2156-97-0
Concentration: > 99%
Impurities: May include traces of acrylic acid, hydroquinone (inhibitor)
Additives: Often stabilized with up to 100 ppm hydroquinone or MEHQ to prevent polymerization during storage and transport

4. First Aid Measures

Inhalation: Move exposed person to fresh air, keep at rest in comfortable position, seek medical advice if symptoms persist
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, seek medical attention for persistent irritation
Eye Contact: Rinse eyes cautiously with clean water for at least 15 minutes, remove contact lenses if present, consult medical personnel if irritation occurs
Ingestion: Rinse mouth, do not induce vomiting, seek medical help promptly
Symptoms: Redness, irritation, itching, possible respiratory discomfort, headache, nausea if overexposed

5. Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, alcohol-resistant foam, CO2, water spray (do not use direct water jet)
Specific Hazards: Vapors may form explosive mixtures with air, thermal decomposition releases acrid smoke, carbon monoxide, and carbon dioxide
Protective Equipment: Firefighters should use full protective gear including self-contained breathing apparatus
Special Precautions: Cool exposed containers with water spray to avoid pressure buildup, avoid runoff into sewers and waterways

6. Accidental Release Measures

Personal Precautions: Evacuate area of unprotected personnel, ventilate space, avoid inhalation and skin contact
Environmental Precautions: Prevent entry into drains, sewers, or waterways, notify authorities if large spill occurs
Methods for Clean-Up: Absorb with inert material (sand, vermiculite), collect mechanically, transfer to labeled leakproof containers for disposal, wash area with detergent and water after collection

7. Handling and Storage

Precautions for Safe Handling: Use in well-ventilated area, keep away from heat sources, sparks, or open flame, avoid contact with eyes and skin, avoid inhalation of vapor
Storage Conditions: Store in tightly closed, properly labeled containers in a cool, dry, ventilated area away from direct sunlight, ignition sources, and incompatible materials like oxidizers, acids, and bases
Incompatibilities: Avoid storage with strong oxidizing agents, acids, bases, or free radical initiators which can cause dangerous reactions including rapid polymerization

8. Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits established, but limit exposure to lowest practicable through proper controls
Engineering Controls: Use mechanical exhaust, capture vapors at point of generation, ensure equipment is explosion-proof
Personal Protection: Wear chemical-resistant gloves (e.g., nitrile), safety goggles or face shield, impervious clothing, and suitable respiratory equipment if airborne exposure possible
Hygiene: Wash hands thoroughly after handling, do not eat or drink in work areas, remove contaminated clothing promptly

9. Physical and Chemical Properties

Appearance: Clear, colorless to slightly yellow liquid
Odor: Mild, acrylic odor
Melting Point: -30°C
Boiling Point: 281°C
Flash Point: 106°C (closed cup)
Vapor Pressure: 0.03 mmHg at 25°C
Solubility: Insoluble in water, miscible with most organic solvents
Density: 0.88 g/cm3 at 20°C
Viscosity: 6 mPa.s at 25°C
Volatility: Low
Partition Coefficient (log Kow): Estimated 4.7
Auto-Ignition Temperature: 270°C
Explosive Limits: Not determined

10. Stability and Reactivity

Chemical Stability: Stable in original container under recommended storage conditions with inhibitor
Polymerization: May polymerize violently under heat, light, or contamination by peroxides, free radical initiators, or strong acids and bases if inhibitor concentration falls
Hazardous Decomposition: Burning may produce acrid smoke, carbon dioxide, carbon monoxide
Conditions to Avoid: Exposure to heat, direct sunlight, strong oxidizers, and initiators
Incompatible Materials: Strong acids, bases, peroxides, free radical initiators

11. Toxicological Information

Acute Toxicity: Oral LD50 (rat): > 5,000 mg/kg; Dermal LD50 (rabbit): > 2,000 mg/kg
Inhalation: May cause headache, dizziness, respiratory tract irritation at high concentrations
Skin Contact: Causes irritation, prolonged exposure may lead to sensitization
Eye Contact: Causes irritation
Chronic Effects: Possible skin sensitization after repeated contact
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, or OSHA
Mutagenicity/Reproductive Toxicity: Existing animal studies show little evidence of mutagenicity or reproductive toxicity at expected exposure levels

12. Ecological Information

Ecotoxicity: Toxic to aquatic organisms, may cause long-term adverse effects in aquatic environment
Persistence/Degradability: Not readily biodegradable, slow degradation in soil and water
Bioaccumulation: Potential to bioaccumulate in aquatic organisms, log Kow indicates moderate to high tendency
Mobility: Limited mobility in environment due to low solubility, but vapor may disperse in air and deposit on surfaces
Environmental Impact: Spill or large release may cause damage to aquatic life, disrupt plant and microbial communities

13. Disposal Considerations

Waste Treatment: Collect residue in sealed, labeled containers, dispose of through licensed hazardous waste facility
Incineration: Suitable method under controlled conditions to avoid emission of toxic byproducts
Avoid Release: Do not pour into drains, surface water, soil, or natural environment
Packaging: Triple rinse empty containers, destroy or recycle per local regulations, avoid reuse for other products

14. Transport Information

UN Number: 1993
UN Proper Shipping Name: Flammable liquid, n.o.s. (Lauryl Acrylate)
Transport Hazard Class: 3 (Flammable liquids)
Packing Group: III
Labels: Flammable liquid
Special Precautions: Protective measures during loading/unloading, avoid container contamination
Environmental Hazards: Classified as hazardous for aquatic environment during shipment

15. Regulatory Information

OSHA Status: Regulated as hazardous chemical
TSCA: Listed
REACH Registration: Required for European Union, may be registered under relevant monomer category
DSL/NDSL (Canada): On Domestic Substances List
WHMIS (Canada): Class B, Division 3 (Combustible Liquid), Class D, Division 2B (Toxic Material causing other toxic effects)
SARA 313: Not listed under toxic release inventory
International Inventories: Listed on AICS, ECL, ENCS, IECSC, NZIoC
Hazard Categories (US): Fire hazard, acute health hazard, chronic health hazard, environmental hazard
Labeling Requirements: Product must include hazard pictograms, signal word, hazard and precautionary statements