Ascent Petrochem Holdings Co., Limited

Knowledge

Material Safety Data Sheet: Hydroxyethyl Acrylate (HEA)

Identification

Product Name: Hydroxyethyl Acrylate (HEA)
Chemical Formula: C5H8O3
CAS Number: 818-61-1
UN Number: 2529
Synonyms: 2-Hydroxyethyl Acrylate; HEA
Recommended Use: Monomer for resins, coatings, adhesives, and sealants
Supplier Details: [Insert Manufacturer Information]
Emergency Contact: [Insert Emergency Phone Number]

Hazard Identification

GHS Classification: Skin Irritation (Category 2), Eye Damage (Category 1), Sensitization (Category 1), Acute Toxicity Oral (Category 4)
Pictograms: Corrosive, Exclamation Mark
Signal Word: Danger
Hazard Statements: Causes severe skin burns and eye damage, may cause allergic skin reaction, harmful if swallowed
Precautionary Statements: Avoid breathing vapors, wear protective gloves, clothing, eye and face protection, wash hands thoroughly after handling, store locked up

Composition / Information on Ingredients

Chemical Name: 2-Hydroxyethyl Acrylate
Concentration: ≥ 96%
Impurities: Trace amounts of acrylic acid, inhibitors such as MEHQ (≤ 200 ppm)
Other Ingredients: Stabilizers or inhibitors as required for safe storage

First Aid Measures

Inhalation: Move person to fresh air, keep comfortable for breathing, seek medical attention for persistent symptoms
Skin Contact: Take off contaminated clothing, rinse skin with water for at least 15 minutes, seek medical advice for irritation or allergic reaction
Eye Contact: Rinse eyes gently with water for at least 15 minutes, remove contact lenses if present, seek immediate medical care
Ingestion: Rinse mouth, never give anything by mouth to an unconscious person, call poison control or seek medical assistance immediately

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, carbon dioxide, dry powder, water spray
Unsuitable Extinguishing Media: Direct water jet, as spattering may occur
Special Hazards: Vapors may form explosive mixtures with air, thermal decomposition can produce acrid smoke, carbon monoxide, carbon dioxide
Protective Equipment for Firefighters: Full protective gear, self-contained breathing apparatus, avoid inhaling fumes

Accidental Release Measures

Personal Precautions: Wear chemical splash goggles, protective gloves, and impervious clothing, ensure adequate ventilation
Environmental Precautions: Prevent spillage from reaching drains, water courses, or soil
Spill Cleanup: Absorb with inert material such as sand or vermiculite, collect into suitable containers for disposal, wash area with water and detergent, ventilate area, dispose according to local regulations

Handling and Storage

Handling: Store and handle in well-ventilated area away from sources of ignition, use explosion-proof equipment, avoid contact with skin, eyes, and clothing, prevent formation of aerosols
Storage: Keep containers tightly closed, store at temperatures between 2°C and 8°C, protect from moisture, sunlight, and heat sources, segregate from oxidizing agents, acids, and bases, store under inhibitor to avoid polymerization

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limit assigned; minimize exposure as much as possible
Engineering Controls: Local exhaust ventilation, enclosures or process isolation, emergency eyewash and shower available
Personal Protection: Chemical-resistant gloves (nitrile or butyl rubber), safety goggles, face shield, impervious apron or lab coat, respiratory protection in case of insufficient ventilation or airborne concentration above recommended levels

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Pungent, slightly acrid
pH: Not available
Melting Point: -13°C
Boiling Point: 96°C at 13 mmHg
Flash Point: 99°C (Closed cup)
Evaporation Rate: Not determined
Flammability: Flammable liquid and vapor
Vapor Pressure: 0.15 mmHg at 20°C
Vapor Density: >1 (air = 1)
Relative Density: 1.10 at 20°C
Water Solubility: Miscible
Partition Coefficient (n-octanol/water): Log Kow 0.33
Auto-ignition Temperature: 280°C
Decomposition Temperature: Not specified
Viscosity: 7 mPa·s at 20°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions with added inhibitors
Reactivity: Reacts with strong acids, bases, oxidizing agents
Hazardous Polymerization: May occur without inhibitor, or exposure to heat, light, contamination
Hazardous Decomposition Products: Acrid smoke, carbon monoxide, carbon dioxide, possibly other toxic gases
Incompatible Materials: Peroxides, free radical initiators, iron, rust, copper, aluminum

Toxicological Information

Acute Toxicity: LD50 (oral, rat) 1020 mg/kg, LD50 (dermal, rabbit) >2000 mg/kg
Skin Corrosion / Irritation: Causes burns and skin sensitization
Eye Damage / Irritation: Causes severe eye damage
Respiratory Sensitization: Sensitization reported in some animal studies
Carcinogenicity: No evidence from current studies
Reproductive Toxicity: Information not sufficient
Other Effects: Prolonged or repeated exposure can cause dermatitis, may aggravate pre-existing skin or respiratory conditions

Ecological Information

Toxicity (Aquatic): Expected to be harmful to aquatic life, EC50 (Daphnia magna, 48h): 19 mg/L
Persistence and Degradability: Readily biodegradable under aerobic conditions
Bioaccumulation: Low potential for bioaccumulation (Log Kow 0.33)
Mobility in Soil: Expected to have high mobility in soil and groundwater
Other Adverse Effects: Avoid contamination of waterways or soil, notify local authorities in event of large spill

Disposal Considerations

Waste Treatment Methods: Dispose of residue and containers according to local, regional, national regulations, incinerate or treat in approved chemical waste facility
Waste Code: May be classified as hazardous waste
Environmental Precautions: Prevent leaks from reaching soil, drains, or water bodies
Packaging Disposal: Triple rinse containers and offer for recycling or disposal according to applicable laws

Transport Information

UN Number: 2529
Shipping Name: Hydroxyethyl Acrylate, Stabilized
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: II
Label: Toxic, Corrosive
Marine Pollutant: Not listed as marine pollutant
Transport Notes: Keep container tightly sealed, transport under cool, ventilated conditions, away from direct sunlight or sources of heat

Regulatory Information

Regulations: Subject to OSHA Hazard Communication Standard, EPA TSCA, REACH registered substance, included on Canadian DSL Inventory
Labeling Requirements: GHS pictograms, hazard statements, precautionary phrases, supplier information
Restrictions: Observe workplace exposure limits, requirements for safe handling, storage, PPE
Other Listings: Not classified as carcinogen by NTP, IARC, OSHA
Additional Requirements: Check local and regional restrictions for use, transportation, and disposal, ensure compliance with environmental and chemical safety laws