Product Name: Glycidyl Methacrylate
Chemical Formula: C7H10O3
CAS Number: 106-91-2
EC Number: 203-441-9
Synonyms: 2,3-Epoxypropyl methacrylate,
Intended Use: Production of polymers, resins, surface coatings, adhesives
Manufacturer: Consult supplier or packaging
Contact Numbers: Refer to product label for emergency phone
GHS Classification: Skin Irritation (Category 2), Eye Irritation (Category 2A), Skin Sensitization (Category 1), Acute Toxicity Oral (Category 4), Specific target organ toxicity - single exposure (Category 3)
Signal Word: Warning
Hazard Statements: Harmful if swallowed; Causes skin and eye irritation; May cause an allergic skin reaction; May cause respiratory irritation
Pictograms: Exclamation mark, Health hazard
Precautionary Statements: Avoid breathing vapors and dust; Use only outdoors or in well-ventilated area; Wear protective gloves/protective clothing/eye protection/face protection
Other Hazards: May form explosive peroxides on prolonged contact with air
Chemical Substance: Glycidyl Methacrylate
Concentration: ≥97%
Impurities: Trace inhibitors (e.g., MEHQ), water, less than 3% combined
Stabilizers: Contains inhibitors to reduce polymerization risk during transport/storage
Inhalation: Move person into fresh air; seek medical advice if symptoms persist (coughing, difficulty breathing)
Skin Contact: Remove contaminated clothing and wash affected skin area thoroughly with soap and water; seek medical attention for irritations or allergic reactions
Eye Contact: Rinse eyes cautiously with water for several minutes; remove contact lenses if present and easy to do; continue rinsing; seek prompt medical attention
Ingestion: Rinse mouth with water; DO NOT induce vomiting; seek immediate medical help
Advice for Medical Personnel: Symptomatic treatment with attention to respiratory and allergic symptoms
Suitable Extinguishing Media: Water spray, alcohol-resistant foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Strong water jets
Special Hazards: May produce toxic fumes such as carbon monoxide, carbon dioxide, and other organics in combustion
Protective Equipment for Firefighters: Self-contained breathing apparatus, protective clothing
Other Information: Containers exposed to fire may be cooled by water fog; avoid inhaling combustion products
Personal Precautions: Evacuate unprotected personnel; avoid breathing vapors and contact with skin or eyes; ensure adequate ventilation
Environmental Precautions: Prevent entry into drains, sewers, or waterways; notify authorities if product enters environment
Cleanup Methods: Absorb spill with inert material (sand, earth), collect in appropriate chemical waste container; wash area with plenty of water; dispose of according to regulations
Precautions for Safe Handling: Avoid contact with eyes, skin, and clothing; avoid breathing vapors; use in well-ventilated areas; employ proper grounding and bonding to avoid static discharge
Handling Instructions: Keep away from heat, sparks, open flames; do not use near sources of ignition; do not eat or drink while handling
Storage Conditions: Store in tightly closed containers in a dry and cool, well-ventilated area; protect from sunlight and sources of heat; keep away from oxidizing agents; use only containers and materials compatible with the chemical
Special Storage Requirements: Store with stabilizer to prevent polymerization
Occupational Exposure Limits: No established specific limits, follow general chemical hygiene standards
Engineering Controls: Use mechanical ventilation, local exhaust, or fume hood to control airborne concentrations
Personal Protective Equipment: Chemical protective gloves (nitrile), tight-fitting safety goggles, protective clothing, use of respirator if ventilation inadequate
Hygiene Measures: Wash hands thoroughly after handling; remove contaminated clothing; do not eat, drink, or smoke while handling product
Appearance: Clear, colorless liquid
Odor: Acrid, characteristic
Melting Point: -52°C
Boiling Point: 189°C
Flash Point: 87°C (closed cup)
Vapor Pressure: 0.35 mmHg at 25°C
Density: 1.07 g/cm³ at 20°C
Solubility: Slightly soluble in water; miscible with most organic solvents
Partition Coefficient Octanol/Water: 1.08
Viscosity: 1.8 mPa•s at 25°C
pH: Not applicable
Chemical Stability: Stable under recommended storage conditions and temperatures; polymerizes when heated, exposed to light, or in the absence of inhibitor
Reactivity: May react violently with strong oxidizing agents, bases, acids, and amines
Hazardous Polymerization: May occur on heating or contamination
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke and fumes
Incompatible Materials: Strong acids, bases, oxidizers, reducing agents
Acute Toxicity: Oral LD50 (rat) roughly 1100 mg/kg
Skin Corrosion/Irritation: Causes skin irritation; may provoke allergic dermatitis
Eye Damage/Irritation: Causes eye irritation
Respiratory Sensitization: May cause respiratory tract irritation
Long-term/Chronic Effects: Prolonged exposure may lead to sensitization
Carcinogenicity/Mutagenicity: No evidence of carcinogenicity in humans; some in vitro evidence of mutagenicity
Other Data: Not classified as reproductive toxin, no known teratogenic effects
Ecotoxicity: Harmful to aquatic life with long lasting effects; aquatic organisms may be impacted at low concentrations
Persistence and Degradability: Not readily biodegradable under environmental conditions
Bioaccumulative Potential: May accumulate in aquatic organisms, low overall bioaccumulation potential due to moderate partition coefficient
Mobility: Low mobility in soil; will volatilize slowly from surface water
Other Harmful Effects: Should not be discharged into environment untreated
Waste Disposal Methods: Incinerate under controlled conditions at facilities meeting local, regional, and national requirements; do not allow material to reach sewer systems
Container Disposal: Empty containers may retain product residues; dispose of containers and contaminated packaging as hazardous waste
Special Instructions: Consult local environmental regulations for disposal advice specific to location
UN Number: 2920
UN Proper Shipping Name: Corrosive Liquid, Flammable, N.O.S. (Glycidyl Methacrylate)
Transport Hazard Classes: 8 (corrosive), 3 (flammable liquid)
Packing Group: II
Marine Pollutant: Not classified as marine pollutant
Special Precautions: Keep containers upright and secure; follow all handling regulations for road, rail, air, and sea transport
Labelling According to GHS: Signal word, hazard statements, pictograms required
TSCA Status (US): Listed
EINECS/ELINCS (EU): Listed
REACH Registration: Required in the European Union
Other Regulations: Subject to workplace exposure monitoring; use restrictions in certain jurisdictions.
Additional Notes: Consult local, state, federal regulations for complete guidance on safe use, transport, and disposal
