Ascent Petrochem Holdings Co., Limited

Knowledge

Material Safety Data Sheet: Ethylene Glycol Diacrylate

1. Identification

Product Name: Ethylene Glycol Diacrylate
CAS Number: 3130-05-6
Synonyms: EGDA
Recommended Use: Crosslinking monomer in polymer production, adhesives, coatings
Manufacturer/Supplier: Check with local supplier or manufacturer
Contact Information: Include company address, emergency contact number, and available hours for inquiries

2. Hazard Identification

Classification: Skin irritation (Category 2), Eye irritation (Category 2A), Skin sensitizer (Category 1), Specific target organ toxicity—single exposure (Category 3: respiratory tract)
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, may cause an allergic skin reaction, may cause respiratory irritation
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing vapors or mist, wear protective gloves and eye protection, wash thoroughly after handling, use only outdoors or in a well-ventilated area

3. Composition / Information on Ingredients

Chemical Name: Ethylene Glycol Diacrylate
CAS Number: 3130-05-6
Concentration: 98–100%
Impurities: Trace inhibitors to prevent polymerization, such as hydroquinone, methyl ether
Other Ingredients: None identified above regulatory thresholds

4. First Aid Measures

Inhalation: Move exposed person to fresh air and keep at rest, get medical attention if symptoms develop or persist
Skin Contact: Remove contaminated clothing, rinse affected skin with soap and water for at least 15 minutes, seek medical help if irritation or rash develops
Eye Contact: Rinse immediately with plenty of water for at least 15 minutes, keeping eyelids open, obtain medical attention straight away
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical assistance
Notes to Physician: Treat symptoms, monitor respiratory function, possible delayed allergic reactions to acrylates

5. Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide or water spray
Unsuitable Extinguishing Media: Do not use direct water stream; may spread fire
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, acrid smoke, potentially toxic acrylate vapors
Firefighting Procedures: Use self-contained breathing apparatus, full protective gear, avoid inhaling combustion gases
Flammability Hazards: Can form combustible mixtures with air in confined areas

6. Accidental Release Measures

Personal Precautions: Wear appropriate personal protective equipment including gloves, safety goggles, respirator if inadequate ventilation exists
Environmental Precautions: Prevent further leakage or spillage if safe, keep out of sewers, waterways or soil
Spill Cleanup Methods: Ventilate the area, contain and collect spillage with inert absorbent material (sand, earth, vermiculite), place in chemical waste container for disposal, decontaminate area with detergent solution

7. Handling and Storage

Handling: Avoid contact with eyes, skin, clothing; do not breathe vapor or mist; use with adequate ventilation; wash hands after handling; ground/bond containers when transferring
Storage: Store in tightly sealed original container in a cool, dry, well-ventilated area away from heat, sunlight, ignition sources and incompatible materials such as strong oxidizers and acids
Storage Conditions: Protect from freezing, keep container upright and closed when not in use, use inhibitor-stabilized formulations to prevent polymerization

8. Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits in US (ACGIH, OSHA)
Engineering Controls: Use local exhaust ventilation, process enclosure, or other engineering controls to maintain exposure below recommended limits
Personal Protective Equipment (PPE): Wear chemical-resistant gloves (butyl rubber, nitrile), safety glasses with side shields, protective clothing (lab coat or apron); if airborne exposure exceeds guidelines, use NIOSH-approved respirator
General Hygiene Measures: Wash hands, face, forearms after handling; remove contaminated clothing and wash before reuse

9. Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Faint, acrylate-like
Melting Point: -40°C
Boiling Point: 220°C
Flash Point: 114°C (closed cup)
Auto-ignition Temperature: Not available
Flammability: Combustible
Vapor Pressure: <0.1 mmHg at 20°C
Density: 1.1–1.16 g/cm³
Solubility: Slightly soluble in water, miscible with most organic solvents
Viscosity: 6–8 mPa·s (at 25°C)
pH: Not applicable (neutral in water)

10. Stability and Reactivity

Chemical Stability: Stable in original, inhibitor-stabilized packaging under recommended storage conditions
Reactivity: Sensitive to heat, light, elevated temperature, and contaminants; can polymerize rapidly under those conditions
Conditions to Avoid: Heat, sunlight, flames, static electricity, contamination with peroxides, acids, alkalis, or other polymerization initiators
Incompatible Materials: Strong oxidizing agents, acids, bases, peroxides
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrylic monomers, potentially irritating acrylate vapors

11. Toxicological Information

Likely Routes of Exposure: Inhalation, skin and eye contact, ingestion
Acute Toxicity: Oral LD50 in rats: 566 mg/kg; can cause mild to moderate irritation on contact
Skin Sensitization: May cause allergic skin reactions in sensitized individuals
Chronic Effects: Prolonged or repeated exposure may aggravate pre-existing skin or respiratory conditions
Carcinogenicity: No information indicating carcinogenic potential for ethylene glycol diacrylate
Other Information: Acrylates in general are known for causing skin sensitization upon repeated or prolonged exposure

12. Ecological Information

Ecotoxicity: Harmful to aquatic life
Aquatic Toxicity: LC50 (fish, 96h): 7.2 mg/L
Persistence and Degradability: Moderately persistent; expected to biodegrade slowly but significantly under environmental conditions
Bioaccumulation Potential: Low; log Kow = 0.445
Mobility in Soil: May leach into ground water if released in large quantity
Other Adverse Effects: Contains no heavy metals or halogenated organic compounds, product spills can cause localized harm to aquatic organisms

13. Disposal Considerations

Waste Treatment Methods: Incinerate at a government-approved facility or dispose of in accordance with local, regional and national regulations
Contaminated Packaging: Triple-rinse containers before disposal, puncture and dispose of in chemical waste stream
Special Precautions: Do not allow material or contaminated rinse water to enter drains or watercourses, avoid landfill disposal where prohibited

14. Transport Information

UN Number: Not classified as dangerous goods under UN Model Regulations
Proper Shipping Name: Not regulated
Transport Hazard Class: Not regulated
Packing Group: Not regulated
Environmental Hazards: Not classified as a marine pollutant
Special Precautions for Transport: Avoid exposure to extreme heat, sunlight; ship in well-sealed containers with adequate labeling; consult national regulations for possible updates

15. Regulatory Information

TSCA Inventory: Listed
REACH Registration: Registered or pre-registered in Europe
Other Worldwide Inventories: Listed on AICS, DSL, IECSC, ENCS, ECL, PICCS
SARA 313: Not subject to reporting
California Proposition 65: Not listed
Label Elements: Conform to current GHS and OSHA HCS (HazCom) labeling requirements
Workplace Restrictions: Follow all occupational safety guidelines regarding acrylate monomers; local, regional, or country-specific guidance may exist