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Ethylene Glycol Diacrylate: A Comprehensive Look

Historical Development

Ethylene Glycol Diacrylate, sometimes called EGDA, first appeared in industrial chemistry research during the mid-20th century. Its roots connect deeply with the expansion of polymer chemistry after World War II. Chemists started looking for compounds that could link long chains together, targeting materials with better toughness, clarity, and chemical resistance. Early patents show EGDA featuring heavily in the search for improved coatings and adhesives. With global manufacturing expanding through the 1970s and onward, this compound started showing up in paints, plastics, and dental materials. Anyone familiar with the rise of the plastics industry remembers how monomer and crosslinker chemicals like EGDA shaped entire sets of products nobody considered possible before.

Product Overview

At its core, EGDA brings together two functional acrylate groups bridged by an ethylene glycol segment. As a colorless, often faintly acrid-smelling liquid, it draws attention on factory floors due to its ability to make crosslinked, durable polymers. Suppliers offer it in containers designed for industrial volumes. The main market delivers EGDA to plastics and specialty chemical companies as a raw material, always seeking materials that will withstand harsh usage conditions, sunlight, and aggressive chemicals. In the world of acrylate crosslinkers, EGDA frequently gets chosen for its predictable behavior and versatility, both in existing processes and experimental blends.

Physical & Chemical Properties

Ethylene Glycol Diacrylate presents itself as a clear or slightly yellow liquid. With a molecular formula of C10H14O4 and a molar mass around 198.22 g/mol, it doesn't stand out by weight, but its double acrylate groups set it apart for reactivity. Its boiling point lands at about 94°C at 1 mmHg, and it carries a density close to 1.09 g/cm³ at 20°C. It dissolves well in a range of organic solvents like alcohols, acetone, and toluene. What makes EGDA essential comes from its two acrylate ends, ready to snap into place during polymerization, locking long chains together and giving finished polymers a leg up against cracks, swelling, or chemical attack.

Technical Specifications & Labeling

Commercial shipments of EGDA need careful labelling. The UN number 1993 marks it as a flammable liquid, and transport rules require clear hazard communication. The purity of EGDA usually sits above 98% for most specialty applications, with inhibitors like hydroquinone monomethyl ether often added to slow unwanted polymerization during storage and transit. Containers get stamped with batch codes, production dates, and safety instructions in multiple languages. Chemists on receiving docks need accurate specs—it’s the only way to match product performance with research targets or manufacturing goals.

Preparation Method

Manufacturing EGDA starts with ethylene glycol and acrylic acid or, more often, acrylic acid esters. Industrial plants commonly use an esterification process, heating ethylene glycol with acrylic acid in the presence of an acid catalyst like sulfuric acid combined with a water-removal system to drive the reaction to completion. After the bulk reaction, distillation removes impurities, and inhibitors help stabilize the finished product before packaging. Over the years, companies have tweaked conditions to improve yields, limit side reactions, and boost batch safety. For anyone involved in chemical process design, EGDA’s preparation highlights decades of incremental improvements that let producers keep pace with stricter safety and purity demands.

Chemical Reactions & Modifications

EGDA stands out for its dual acrylate groups, each primed for rapid addition reactions, especially free-radical polymerization. Add a little benzoyl peroxide, expose the mix to light or heat, and those acrylate ends fire off into long chains, linking together factsers or copolymerizing with other vinyl compounds. EGDA forms denser, tighter networks than monoacrylates, making it a favorite for forming highly crosslinked resins. Modified EGDA, with tweaked glycol sections or substituted acrylates, opens doors to polymers with custom flexibility, resistance, or processing windows. In academic and commercial labs, tinkerers constantly adjust EGDA concentrations to bend the final product toward toughness, transparency, or chemical inertness.

Synonyms & Product Names

Across chemical supply catalogs EGDA pops up with several names: 1,2-Ethanediol diacrylate; Ethylene diacrylate; and its CAS number 3130-05-6 are all common synonyms. Major chemical manufacturers roll out trade names, sometimes tacking EGDA onto a longer proprietary name or plugging it as a component of pre-blended resin systems. Despite the variety, the label always flags the dual acrylate nature, which clues in trained buyers on what to expect in terms of reactivity and use.

Safety & Operational Standards

Anyone handling EGDA needs to respect its hazards. Its vapor can irritate eyes and respiratory passages, and skin contact may lead to allergic reactions, especially among sensitized workers. Flammable warnings show up on every drum. Facilities follow strict guidelines: good ventilation, grounded tanks to prevent sparks, chemical-resistant gloves, splash goggles, and quick access eyewash stations form only the baseline. Spill protocols are drilled into staff, and unused material gets stored under nitrogen or in the dark to fend off runaway polymerization. Because chronic exposure may raise health concerns, regular monitoring and blood testing programs cover those most at risk. Workers count on reliable training—mistakes here turn dangerous in seconds.

Application Area

EGDA finds its way into a staggering list of industrial and consumer products. In the paint, ink, and adhesive markets, EGDA delivers strength and chemical durability, letting manufacturers deliver coatings that handle constant abrasion or contact with harsh cleaning agents. The dental materials sector uses EGDA for light-cured fillings and sealants, relying on its balance between flow and final hardness. Electronics fabrication sometimes chooses EGDA-linked resins for solder masks and protective chip coatings. In 3D printing, EGDA brings shape retention and surface smoothness critical for prototypes and functional parts alike. Year by year, as new polymer technologies roll out, EGDA holds on as a reliable crosslinker, connecting ideas from research benches to factory lines.

Research & Development

Chemists keep looking for new tricks using EGDA as a building block. Materials scientists combine it with nanoparticles for coatings that resist everything from graffiti to bacteria growth. Biomedical engineers experiment with EGDA-modified hydrogels for drug delivery and tissue engineering scaffolds, chasing that sweet spot of softness and durability. Research teams use its well-understood chemistry to anchor complex molecules or sensors onto larger platforms. Because new markets always demand something tougher, clearer, or more flexible, EGDA remains a standard benchmark and a frequent subject of optimization.

Toxicity Research

Toxicologists examine EGDA’s effects through multiple lenses. Tests in lab animals reveal low-to-moderate acute toxicity, but long-term exposure—especially via skin or inhalation—raises bigger worries. Eye and skin irritancy tests force regulators to label it as a sensitizer. Occupational exposure studies suggest increased allergies among workforce segments with repeated contact. Environmental studies highlight slow biodegradation and some aquatic toxicity. These findings haven’t stopped its use but have forced upgrades to personal protection, spill response design, and air handling requirements inside production sites. Regulators from the US EPA to the European Chemicals Agency watch EGDA use closely, demanding better data and safer application methods every year.

Future Prospects

Product developers and researchers do not stop searching for better crosslinkers or sharper performance in their materials. Next-generation 3D printing resins under testing in labs around the world often use EGDA in new blends, pushing print speed and detail as far as possible. Green chemistry pushes producers toward cleaner synthesis pathways and less toxic stabilizers. As electronics shrink and medical devices grow more complex, the need for stable and customizable acrylates keeps EGDA in the discussion. The trick will be balancing its powerful chemistry with greater attention to safety and sustainable lifecycle management, making sure progress doesn't leave behind hidden costs to people or the environment.



What is Ethylene Glycol Diacrylate used for?

Pushing Plastics to Perform

Factories and research labs keep coming back to ethylene glycol diacrylate when they need plastics that can take a beating. Picture the clear lens in your sunglasses or the body of your dental fillings—these products demand strength and a finish that sticks around. I’ve seen plastics buckle and warp over months, but when ethylene glycol diacrylate joins the mix, the plastic builds a tighter, cross-linked network. It stretches less, cracks less, and ends up more resistant to everything from heat to everyday chemicals. That’s the difference between a product lasting a season and one lasting years.

Makers and Dental Clinics: Everyday Uses

This chemical shows up at the dentist’s office more than most people realize. Fillings, sealants, and even some dentures use compounds based on ethylene glycol diacrylate. Dentists rely on it because it reacts quickly under UV light, hardening materials in seconds. That means fewer long appointments and better comfort for patients. Dental resins count on this efficiency—UV-curing isn’t just about speed, it helps lower costs and cuts waste, which patients appreciate during every visit.

On manufacturing floors, people blend this chemical into paints and coatings to make surfaces tougher. The automotive world especially watches for weather resistance, impact strength, and clear coating stability. Ethylene glycol diacrylate delivers that blend of properties without breaking budgets or pulling supply chains through complicated loops.

Addressing Worker Safety and Environmental Impact

One concern comes up every time chemicals hit the shop floor: safety. Nobody wants a headache from fumes or raw skin after an eight-hour shift. Workers deal with ethylene glycol diacrylate in liquid form before it cures, so factories install exhaust fans, gloves, and occasional mask requirements. It’s all about keeping exposure low. Outside the plant, questions swirl around chemical runoff and waste. Water treatment facilities move to break down leftover material, and regulations push disposal standards higher each year. What I’ve seen in recent years is more investment in recycling and research, not as an expensive box to tick but because the stakes for communities near these plants can’t be ignored.

Room for Improvement

If we’re honest, there’s no silver bullet in materials science. Plastics using ethylene glycol diacrylate offer serious durability, but recycling cross-linked plastics still frustrates waste managers. Mechanical recycling struggles since the hardened network doesn’t melt down easily for second-life products. Companies are working on new additives and processing techniques to open up more recyclable options. Governments reward this innovation with grants and quicker regulatory approvals.

Looking Ahead

People expect products to last and companies know that trust doesn’t come cheap. Ethylene glycol diacrylate supports strong, lasting goods in fields from healthcare to auto repair. Scientists keep searching for ways to balance better performance with eco-friendly design. For anyone concerned with quality—and with the world their kids will inherit—paying attention to these behind-the-scenes chemistry decisions matters.

What are the safety precautions when handling Ethylene Glycol Diacrylate?

Understanding the Chemical’s Hazards

Ethylene Glycol Diacrylate (EGDA) often turns up in plastics, coatings, adhesives, and inks. I still remember my first chemistry lab where a spilled sample stung my nose—this stuff carries a noticeable smell, and a not-so-subtle way of telling you it’s trouble if handled carelessly. EGDA irritates skin, eyes, and lungs. Breathing in the fumes feels rough. Long-term or heavy exposure sometimes triggers skin sensitization, rashes, or even more severe health problems. Experts recommend careful handling because, even in small doses, direct skin and eye contact can leave a mark.

Personal Protection

Whenever EGDA lands on the worktable, consider it a high-priority hazard. I reach for nitrile gloves instead of standard latex; EGDA seeps through cheaper gloves before you know it. Splash-proof safety goggles come next. It only takes a drop to hurt your vision. Comfortable but tightly sealed goggles or a face shield stand between us and the stinging irritation. For anyone pouring or mixing, a lab coat or a chemical-resistant apron makes life easier at the end of the day—no surprise stains or skin problems. Closed-toed shoes keep accidents from turning worse.

Proper Handling in the Workspace

I keep EGDA work in a fume hood or at least in a room with active exhaust fans. This chemical off-gasses, filling an unventilated room with enough fumes to trigger headaches and coughing fits. Spills need quick, thorough cleaning. Absorbent pads pick up larger messes; paper towels just move puddles around. I’ve seen coworkers skip over ventilation or gloves trying to finish quickly. Rushed handling brings long-term regrets. All containers must stay sealed and labeled. Unmarked or loosely capped bottles endanger anyone sharing the workspace. Safety data sheets belong within reach, always readable when questions or emergencies strike.

Storage Solutions

EGDA rarely explodes or catches fire, but storing it in a cool, dry, ventilated place drops the risk further. Direct sunlight heats up the bottle, pressurizing contents, or sometimes breaking them down. Acid or base residues on shelves mess with the chemical’s stability. I keep EGDA separate, sharing a cabinet only with similar low-risk monomers or resins. Once I saw a shared shelf of random chemicals take on a sticky, sweet odor as cross-contamination spoiled whole batches—costs everyone more in the long haul. Proper spill kits belong nearby, stocked with neutralizer, absorbent, and waste bags rated for acrylates.

Disposal Duties

EGDA waste doesn’t go down the drain. Local rules usually require labeling hazardous waste and calling in certified disposal crews. Back in my university lab, mishandled waste filled the building with overpowering smells and forced an evacuation. Waste containers should seal fully and resist leaks. Label each one with the chemical’s name, source, and collection date. Old or expired material never gets mixed with other chemicals before disposal—it complicates cleanup and hikes the cost. Clean-up wipes and PPE go into hazardous waste bags, not regular trash. If rules allow, a special waste treatment system neutralizes smaller amounts, but always after triple-checking it won’t cause dangerous reactions.

Building Safer Routines

Routine training makes a big difference. New lab members learn the risks as soon as they walk in. I’ve lost count of the “near-misses” a quick reminder prevented. Regular gear checks, safety drills, and updated reference posters keep safety on everyone’s mind. If something spills, reporting and cleaning beats hiding the mess—no one wants to step into danger because someone else took shortcuts. EGDA gives back solid results in composites, adhesives, and coatings, but it demands respect and care from start to finish.

What is the shelf life and storage condition for Ethylene Glycol Diacrylate?

A Deep Look into Ethylene Glycol Diacrylate’s Longevity

If your workspace involves chemicals like Ethylene Glycol Diacrylate (EGDA), understanding shelf life and proper storage keeps you safe and saves money. In my years working with resins and monomers, chemical surprises rarely turn out well. This diacrylate gets attention because it reacts easily and handles UV curing like a champ. Yet, what’s clear in the industry: what goes in the bottle isn’t immortal—its quality can take a hit over time or in the wrong conditions.

Shelf Life Demands Attention, Not Hope

Manufacturers usually say EGDA holds up for about one year from the date of manufacture—sometimes up to two if you get a perfectly sealed drum and baby it. That number comes with a disclaimer: temperature swings, open containers, or just sitting untouched too long can shorten EGDA’s working life fast. This isn’t just a number picked out of thin air. EGDA breaks down if it gets hit with heat or UV, and its peroxide stabilizer works only as long as nobody overloads it. I can tell you more than once someone’s tried to use that half-empty jug after eighteen months, and the results rarely pass quality checks.

What Messes Things Up?

EGDA doesn’t need much provocation. Heat, oxygen, or sunlight can all kickstart premature polymerization (in other words, it starts setting up in the bottle). After that, what’s left inside won’t act right in your formulations. I’ve seen sticky, unusable clumps come out of containers that sat in a warm storage closet, especially if someone forgot to reseal the lid tight. Even a quick batch test with old EGDA can waste hours if you’re betting on expired material.

Keep It Fresh or Take the Loss

Figuring out how to make EGDA last comes down to a few habits. Store it in cool, dry, and dark places—ideally below 25°C. Never let direct sunlight touch the containers. Always close jugs or drums tightly after every use. If your facility tracks open batches by marking the dates, it saves headaches later. I learned fast not to trust generic "chemical storage" racks placed next to machinery or heat sources because slow bake equals a short shelf life.

Testing and Monitoring Matter

Putting faith in a "best by" date makes accidents more likely. Regular inspection matters—if you catch any crystals, clumps, or strange smells, don’t roll the dice. Most labs run a quick test by taking a small sample, checking for color change or thickening, or even small-scale reactivity tests before big runs. This costs a fraction compared to wasted products or the safety risks tied to runaway reactions with degraded chemicals.

Cutting Down on Waste

Inventory rotation helps—fresh drums up front, older supplies used first. Sharing accurate shelf-life information across departments builds trust and avoids slipping expired EGDA into formulations. Digital tracking tools or plain old labels on the container can reduce mix-ups. I’ve seen facilities save thousands just from routine training sessions on chemical storage and handling alone. Waste less, risk less—those lessons translate to fewer headaches for everyone on the job.

Is Ethylene Glycol Diacrylate compatible with other acrylate monomers?

Understanding Ethylene Glycol Diacrylate’s Fit with Other Monomers

Ethylene glycol diacrylate (EGDA) always draws chemists and engineers for one simple reason: it locks together molecules to shape tough, crosslinked materials. This backbone-building action matters in a world demanding better plastics, coatings, adhesives, and dental composites. The talk on the lab bench often circles back to compatibility between EGDA and other acrylate monomers. Crosslinkers like EGDA have the power to influence strength, viscosity, flexibility, and even how safe a product feels in your hands. Nobody wants a sticky mess or a brittle failure in a final product.

Anyone who’s spent time formulating UV-cured coatings or resins knows that acrylate monomers come in many flavors: simple ones like methyl acrylate, flexible ones like butyl acrylate, sticky favorites like 2-ethylhexyl acrylate, and specialty monomers with all sorts of added groups for better adhesion or flexibility. They all react using the double bonds, free radicals, and initiation systems that make acrylate chemistry both rewarding and unpredictable.

What the Science Shows

Solid experimental evidence supports the use of EGDA in blends with monoacrylates and other polyacrylate crosslinkers. Peer-reviewed articles, such as those from the Journal of Polymer Science and Macromolecules, routinely discuss EGDA-slanted copolymerizations. They report that EGDA partners up nicely in the chain reaction, lining up its diacrylate groups to stitch long polymer networks. Adding a dash of EGDA to a monomer blend often quickens curing, boosts heat resistance, and stops finished materials from softening on a warm day.

The crucial test comes in the hands-on mixing and curing. That’s where the differences really pop up: too much EGDA, and the product gets glassy and shrinks; too little, and it’s weak or sticky. The literature and industry practices help keep things on track. Data from suppliers such as Sigma-Aldrich, as well as regulatory documents from ECHA, underline that EGDA plays well with most common acrylate monomers under standard photoinitiation conditions. No dramatic incompatibilities turn up on safety data sheets or in peer formulation discussions.

Why Compatibility Stays Important

Anyone formulating adhesives or dental resins has run into challenges matching the cure schedules, viscosities, and physical strengths needed for products. It may read like a technical itch, but compatibility here shapes whether a product goes to market or ends up as waste. With acrylates, shelf stability and predictable performance all revolve around reliable chemistry between monomers and crosslinkers like EGDA. There’s nothing quite as frustrating as a resin blend that phase-separates, cures unevenly, or spits out bubbles under the heat lamp.

Personal experience as a lab tech in a coatings company taught me the pain of dealing with incompatible blends. Swapping out one crosslinker for another in an acrylic resin led to separated layers, tacky films, and annoyed customers. Learning to check technical papers, supplier recommendations, and then confirm everything by running a few trial batches set me straight. Acrylates reward careful, honest experimentation. EGDA, in practical terms, delivers predictable, sturdy cures so long as you treat it with respect and balance in the recipe.

Where to Go from Here

Folks in the lab or on the production floor can keep surprises to a minimum by using supplier formulation guides, following tested ratios, and running pilot batches before scaling up. This minimizes waste, builds confidence, and helps ensure that products will hold up whether used in a dental filling, UV-cured finish, or a pressure-sensitive adhesive.

Mixing EGDA with acrylates doesn’t guarantee perfection, but ongoing research, practical insight from seasoned chemists, and a willingness to learn from mistakes can keep innovation moving forward without wasted time or disappointed end users.

What are the typical packaging sizes for Ethylene Glycol Diacrylate?

Why Packaging Size Matters in Industry

Ethylene Glycol Diacrylate (EGDA) turns up in all sorts of composite, adhesive, and coating jobs. Production managers often look at the container size before making a purchase, not just the chemical qualities. No one wants to over-order and tie up money in drums that gather dust, or run out mid-batch and scramble for an emergency supply.

Common Options on the Market

In a standard chemical warehouse, you’ll find EGDA sold in multiple package sizes. Lab-scale researchers grab the 500-gram or one-liter bottles. Factories, especially those churning out resins or advanced polymers, prefer 20-kilogram pails or even 200-kilogram drums. These volumes match the scale of most batch reactor runs or blending operations.

Some suppliers even offer custom tote sizes, like 1,000-liter intermediate bulk containers, for customers with hungry production lines. Smaller containers benefit from easier handling and quicker turnover, keeping the product fresher; bigger packages save money by cutting cost per kilo.

Safety, Storage, and Transport

EGDA brings safety rules to the table. The chemical reacts with light and air if left out too long, so companies stick with steel drums or high-density polyethylene jugs that block out sunlight. This keeps the substance stable, and helps avoid expensive waste. No one wants leaks either, so caps seal tight and every shipment comes with extra hazard labeling.

Shipping rules steer companies away from oddball container sizes. Logistics teams prefer standard pails, drums, and totes because they slot neatly onto pallets, truck trailers, or warehouse racks. Oversized or oddly-shaped packages slow everything down. Keep it simple and a supply chain keeps humming.

The Price Breaks at Scale

Buyers eyeing EGDA costs soon spot the price breaks. By ton, the big drums or totes win hands down compared to a stack of small bottles. Smaller labs tolerate the extra markup for the convenience, but plants with bigger demand almost always move up to barrels quickly.

Bulk deliveries also help producers dodge extra plastic and cardboard waste. Fewer packages mean fewer empty drums piled out back, less residue to wash out, and fewer headaches for environmental compliance teams. Cutting packaging waste isn’t just a green badge—it knocks out disposal costs.

Room for Improvement

Not every factory shares the same needs, so packaging flexibility matters. While bottles and drums cover most applications, producers could do more to help customers scale up or down without overpaying. Adjustable-quantity programs or refill systems would find support among mid-sized buyers—especially those balancing price, storage, and environmental compliance.

Suppliers win customer trust by getting both the physical package and the back-office documentation right. Accurate safety paperwork, lot traceability, and batch consistency make a bigger impact than new container shapes or clever labeling.

Getting the Right Fit

From my own experience in industrial supply, few buyers regret sizing up their orders or pooling together for bulk purchases once operations hit a certain scale. The only real mistakes come from guessing what you’ll need or from bucking safety to shave a few dollars off freight. Asking questions and reviewing production plans often saves more time and money than shopping by price alone.

EGDA isn’t a commodity you buy once and forget. Matching your packaging size to your needs keeps production steady and budgets healthy. A little planning helps every barrel roll in just when you need it.

Ethylene Glycol Diacrylate