Ascent Petrochem Holdings Co., Limited

Knowledge

Material Safety Data Sheet: Diethylene Glycol Dimethacrylate

Identification

Product Name: Diethylene Glycol Dimethacrylate
Chemical Formula: C12H18O6
CAS No.: 2358-84-1
Synonyms: 2-Propenoic acid, 2-methyl-, diester with diethylene glycol
Recommended Use: Monomer, industrial polymer production, adhesives, coatings
Supplier: Check product label or invoice for up-to-date supplier information
Emergency Contact Number: Refer to local/national poison control center or supplier’s emergency contact from packaging

Hazard Identification

GHS Classification: Skin irritant (Category 2), Eye irritant (Category 2A), Skin Sensitizer (Category 1), Specific target organ toxicity – single exposure (Category 3)
Pictogram: Exclamation mark
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, may cause allergic skin reaction, may cause respiratory irritation
Precautionary Statements: Avoid breathing vapors, use protective gloves and eyewear, wash skin thoroughly after handling
Routes of Exposure: Inhalation, skin and eye contact

Composition / Information on Ingredients

Chemical: Diethylene Glycol Dimethacrylate
Concentration: >95%
Impurities: Trace stabilizer, possible inhibitors (hydroquinone, methyl ether); check Certificate of Analysis for actual impurity details
CAS Number: 2358-84-1
Other Components: Typically less than 1% polymerization inhibitors and trace solvents

First Aid Measures

Inhalation: Remove to fresh air, keep at rest, monitor breathing, seek medical advice if symptoms occur
Skin Contact: Remove contaminated clothing, wash with soap and water, do not use solvents, seek medical help for irritation
Eye Contact: Rinse eyes with water for at least 15 minutes, avoid rubbing, seek medical attention immediately
Ingestion: Rinse mouth, do not induce vomiting, drink water if conscious, get medical aid quickly
Most Important Symptoms/Effects: Redness, irritation, possible allergic reaction
Notes to Physician: Treat as chemical exposure; symptomatic and supportive care

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry chemical, carbon dioxide, water fog
Unsuitable Media: Direct water stream may spread fire
Specific Hazards: Vapors may form explosive mixtures with air, hazardous decomposition may include carbon oxides, acrid smoke, noxious fumes
Protective Equipment: Wear self-contained breathing apparatus, full protective gear, keep upwind of fire
Special Procedures: Cool exposed containers with water spray, contain contaminated runoff

Accidental Release Measures

Personal Precautions: Ventilate area, evacuate unnecessary personnel, avoid breathing vapors, use proper PPE (gloves, goggles, mask)
Environmental Precautions: Prevent runoff to water bodies, contain spillage with inert materials
Methods for Containment: Dike and absorb with sand, earth, or vermiculite
Clean Up Procedures: Collect in closed, labeled containers, ventilate area, dispose according to regulations
Decontamination: Wash spill area with water and detergent after cleanup

Handling and Storage

Precautions for Safe Handling: Use in well-ventilated places, ground/bond containers, avoid skin and eye contact, keep away from ignition sources
Storage Conditions: Store in cool, dry, fire-proof areas, tightly closed containers, use lights/exhausts with explosion-proof features
Incompatible Materials: Strong oxidizers, acids, bases, free radical initiators
Special Practices: Keep away from food and drinks, label containers clearly, keep out of reach of children

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific limits established; minimize exposure as for other acrylate monomers
Engineering Controls: Use local exhaust ventilation, maintain eye wash station, design closed systems for transfers
Personal Protective Equipment: Gloves (nitrile, neoprene), goggles or face shield, chemical resistant clothing, approved respirator for high vapor areas
Hygiene Measures: Wash hands and face after handling, remove contaminated clothing

Physical and Chemical Properties

Appearance: Clear, colorless to light yellow liquid
Odor: Mild acrylate odor
Melting Point/Freezing Point: Not readily available; product usually liquid at room temperature
Boiling Point: Approx. 220°C
Vapor Pressure: Low (0.008 mmHg at 20°C)
Density: 1.08–1.09 g/cm3 at 20°C
Solubility: Slightly soluble in water, miscible with various organic solvents
Flash Point: Approx. 124°C (closed cup)
Auto-ignition Temperature: >250°C
Explosion Limits: Not well established
Viscosity: Relatively low, specific value varies by supplier

Stability and Reactivity

Chemical Stability: Stable if stored and handled as recommended; sensitivity to light, heat, peroxides, and radical initiators
Reactivity: Reacts with oxidizing agents, acids, bases
Hazardous Polymerization: May occur in absence of inhibitor or under heat—store with proper inhibitor and away from sunlight
Decomposition Products: Acrid smoke, carbon oxides, methacrylates
Conditions to Avoid: Heat, light, sparks, incompatible materials

Toxicological Information

Acute Toxicity (Oral): LD50 (rats): Approx. 5000 mg/kg
Inhalation: Vapors can cause respiratory irritation
Dermal: May cause irritation and allergic reactions
Eye Effects: Can cause severe irritation and possible damage
Chronic Effects: Evidence of sensitization and dermatitis from repeated exposures
Carcinogenicity: No evidence in animal studies, not listed by IARC, NTP, or OSHA
Mutagenicity: No conclusive data, handle as potential risk

Ecological Information

Ecotoxicity: Toxic to aquatic life with long-lasting effects
Persistence and Degradability: Not rapidly biodegradable
Bioaccumulation: No significant potential observed
Mobility in Soil: Likely to leach, low adsorption to soil particles
Other Adverse Effects: Harmful to aquatic plants and invertebrates

Disposal Considerations

Waste Disposal Methods: Dispose via licensed waste disposal contractor, incinerate under controlled conditions, do not pour into drains or environment
Container Disposal: Rinse thoroughly, puncture and recycle if permitted, label as hazardous for disposal
National/Regional Regulations: Follow all local environmental and hazardous waste regulations

Transport Information

UN Number: 1993
UN Proper Shipping Name: Flammable Liquid, N.O.S. (contains Diethylene Glycol Dimethacrylate)
Transport Hazard Class: 3 (Flammable liquid)
Packing Group: III
Marine Pollutant: Yes
Environmental Hazards: Harmful to water environments
Special Precautions: Label according to national and international transport regulations, keep containers upright and sealed

Regulatory Information

OSHA: Not specifically regulated, covered under general chemical safety regulations
TSCA: Listed
REACH: Registered or pre-registered in EU
SARA 313: Not listed
California Proposition 65: Not listed as of latest update
Other Regulations: Check national and regional restrictions or reporting requirements, use control measures for workplace exposures