Ascent Petrochem Holdings Co., Limited

Knowledge

Material Safety Data Sheet (MSDS): Biological Acrylate

Identification

Product Name: Biological Acrylate
Chemical Family: Acrylate esters derived from renewable biological sources
Synonyms: Bio-based acrylate, Renewable acrylate monomer
Manufacturer/Supplier: [Insert company name and contact details]
Recommended Use: Resin production, coatings, adhesives
Emergency Contact Number: [Insert emergency number]
Product Code: [Insert code]
Date of Preparation: [Insert date]

Hazard Identification

GHS Classification: Skin and eye irritant, possible sensitizer
Signal Word: Warning
Hazard Statements: May cause skin irritation, eye irritation, allergic skin reaction
Precautionary Statements: Avoid contact with skin and eyes, use personal protective equipment (PPE) as instructed
Pictograms: Irritant (exclamation mark), Health hazard symbol
Potential Health Effects: Prolonged exposure may trigger dermatitis or respiratory discomfort
Environmental Hazards: Not classified as hazardous to the environment at typical concentrations; avoid release to surface waters

Composition / Information on Ingredients

Substance: Biological Acrylate (single component or blend)
Chemical Formula: CnHmO2 (varies by exact bio-feedstock and ester group)
CAS Number: [Insert CAS number]
Concentration: >95% acrylate monomers
Impurities: Trace levels of bio-based alcohols, stabilizers (typically <1%)
Additives: Hydroquinone or other polymerization inhibitors (as required for storage stability)

First Aid Measures

Inhalation: Move affected person to fresh air immediately, keep them calm and comfortable, seek medical attention if respiratory symptoms persist
Skin Contact: Remove contaminated clothing, wash thoroughly with soap and water, seek medical attention if irritation develops
Eye Contact: Rinse with copious amounts of water for at least 15 minutes, holding eyelids open, remove contact lenses if present and continue rinsing, seek medical attention immediately
Ingestion: Rinse mouth with water, do not induce vomiting, seek immediate medical attention
Important Symptoms: Redness, irritation, burning sensation, possible blistering in severe cases
Special Advice for Physician: Symptomatic treatment based on clinical findings

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry chemical powder, carbon dioxide, water spray (avoid direct water jet to prevent spread)
Specific Hazards: Vapors may form explosive mixtures with air, can give off toxic fumes (e.g., carbon monoxide, acrylic vapors) under fire conditions
Protective Equipment: Full protective gear, self-contained breathing apparatus
Other Precautions: Remove all ignition sources, keep containers cool with water spray, prevent runoff into drains

Accidental Release Measures

Personal Precautions: Use appropriate PPE including gloves, goggles, respirators if vapor concentrations are high
Environmental Precautions: Prevent spill from reaching soil, sewers, or waterways; notify authorities according to local regulations
Cleanup Methods: Contain spill with inert absorbent (e.g., sand, diatomaceous earth), collect absorbent material for proper disposal, ventilate the spill area, wash down small residues with plenty of water

Handling and Storage

Handling: Use in well-ventilated areas, keep away from heat and all sources of ignition, avoid inhalation or direct skin contact, wash hands after handling
Storage Conditions: Store in tightly closed original containers in a cool, dry, well-ventilated area, keep away from sunlight and incompatible materials such as strong oxidizers and bases, maintain inhibitor levels as prescribed to prevent unwanted polymerization
Incompatibilities: Strong acids, bases, oxidizers, and free radical initiators
Special Storage Concerns: Protect from moisture and temperature extremes, regular inspection for container integrity recommended

Exposure Controls and Personal Protection

Exposure Limits: No specific OSHA or ACGIH exposure limits for biological acrylates; general guidance follows similar acrylate monomers (typically TWA 1-5 ppm)
Engineering Controls: Ensure proper exhaust ventilation at processing sites
Respiratory Protection: Use NIOSH-approved respirator if airborne concentrations rise above guidelines or if recommended by a risk assessment
Hand Protection: Wear chemical-resistant gloves (nitrile or neoprene preferred)
Eye Protection: Safety goggles with side shields
Skin Protection: Wear long sleeves and chemically resistant lab coats or aprons
Hygiene Measures: Wash hands, forearms, and face thoroughly after handling; launder contaminated clothing before reuse

Physical and Chemical Properties

Physical State: Clear to slightly yellow liquid
Odor: Mild acrylate odor, sometimes sweet depending on feedstock
Odor Threshold: Low, detectable at concentrations less than 1 ppm
pH: Not applicable (neat liquid)
Melting Point/Freezing Point: -20 to 0°C (varies by chemical structure)
Boiling Point: 150-200°C
Flash Point: 70-100°C (closed cup)
Evaporation Rate: Slower than diethyl ether
Flammability: Flammable liquid category 3
Vapor Pressure: 0.1 - 2 mmHg at 20°C
Vapor Density: Heavier than air
Solubility: Limited solubility in water, soluble in organic solvents
Viscosity: 10-200 mPa·s (varies)
Partition Coefficient (n-octanol/water): Estimated log Kow 1.5 - 3
Autoignition Temperature: >250°C
Decomposition Temperature: >200°C

Stability and Reactivity

Chemical Stability: Stable if stored as directed and protected from contamination and heat
Reactivity: Can undergo uncontrolled polymerization if exposed to high heat, strong UV, or free radicals
Conditions to Avoid: Elevated temperatures, direct sunlight, sources of ignition, incompatible materials
Hazardous Decomposition Products: Carbon oxides, acrylate vapors, possible organic acids
Polymerization Risks: Inhibited with polymerization inhibitors, risk increases if stored without appropriate protection

Toxicological Information

Acute Toxicity: Oral LD50 (rat): >2000 mg/kg; Dermal LD50 (rabbit): >2000 mg/kg
Skin Corrosion/Irritation: Expected to cause skin irritation; risk increases with prolonged contact
Serious Eye Damage/Irritation: Eye contact can result in moderate to severe irritation
Respiratory or Skin Sensitization: Some acrylate monomers can trigger allergic skin reactions in sensitive individuals
Carcinogenicity: Not listed as a carcinogen by OSHA, IARC, NTP
Reproductive Toxicity: No evidence from animal studies at typical exposure levels
Other Effects: Inhalation exposure may cause respiratory discomfort, headaches, dizziness

Ecological Information

Acute Aquatic Toxicity: LC50 (Fish, 96h): >100 mg/L (low aquatic toxicity)
Chronic Aquatic Toxicity: No significant bioaccumulation expected
Persistence and Degradability: Biodegradable under aerobic conditions, degradation rate dependent on structure and local conditions
Mobility in Soil: Moderately mobile in soil, can leach to groundwater under heavy spill conditions
Other Adverse Effects: Spill may cause short-term oxygen depletion due to high oxygen demand during biodegradation

Disposal Considerations

Waste Disposal Methods: Collect liquid waste for incineration or chemical processing in accordance with local, regional, and national regulations
Container Disposal: Triple rinse empty containers and offer for recycling or disposal at qualified hazardous waste sites
Precautions: Avoid disposal to landfills, surface water, or incompatible municipal sewer systems

Transport Information

UN Number: UN1993 (if applicable based on flammability)
Proper Shipping Name: Flammable liquid, n.o.s. (Contains biological acrylate)
Transport Hazard Class: 3 (Flammable liquid)
Packing Group: III
Labels Required: Flammable liquid symbol
Special Precautions: Ensure containers are tightly closed, labeled, and comply with applicable transportation regulations on land, sea, or air

Regulatory Information

TSCA Inventory: All starting materials listed or exempt
REACH Registration: Compliant - meets pre-registration requirements for polymers and monomers
OSHA Status: Regulated as a hazardous chemical; refer to OSHA 29 CFR 1910.1200
SARA 313: Not listed for reporting at present
California Proposition 65: Not known to contain listed substances at reportable levels
Other: Product meets many voluntary program guidelines for safer chemistry and renewable sourcing; users should verify compliance with local and national chemical safety laws