Product Name: Bio-Tetrahydrofurfuryl Methacrylate
Synonyms: THFMA
Chemical Formula: C9H14O4
CAS Number: 2455-24-5
Recommended Use: Polymer manufacturing, coatings, adhesives
Manufacturer: [Insert Manufacturer’s Name and Address]
Emergency Contact: [Insert Contact Number]
Import/Distribution: [Insert Relevant Details]
Classification: Eye irritation (Category 2A), Skin irritation (Category 2), Sensitizer (Category 1)
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, May cause allergic skin reaction
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing vapors, Use only outdoors or in well-ventilated area, Wear protective gloves/eye protection
Known Symptoms: Redness, itching, rash, burning of mucous membranes
Chemical Identity: Tetrahydrofurfuryl Methacrylate
CAS Number: 2455-24-5
Concentration: ≥ 98%
Impurities: Methacrylic acid (≤ 0.2%), water (≤ 1%)
Inhalation: Move to fresh air, keep at rest. Seek medical attention if symptoms develop.
Skin Contact: Remove contaminated clothing, wash skin with soap and water for at least 15 minutes.
Eye Contact: Rinse immediately with plenty of water. Remove contact lenses. Continue rinsing for at least 15 minutes. Consult a doctor.
Ingestion: Rinse mouth, do not induce vomiting. Seek immediate medical attention.
Note to Doctors: Treat symptomatically and supportively, no specific antidote known.
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: Direct water jet
Specific Hazards: Combustion produces toxic fumes including carbon oxides, irritating vapors
Protective Equipment: Firefighters require self-contained breathing apparatus, full protective clothing
Other Advice: Cool exposed containers with water spray. Avoid breathing vapors. Evacuate area if safe operation is compromised.
Personal Precautions: Wear chemical-resistant gloves, goggles, and protective clothing. Provide adequate ventilation.
Environmental Precautions: Prevent entry into sewers, surface water, or soil. Notify authorities if large spill occurs.
Containment: Stop leak if safe. Contain spill with sand, earth, or other non-combustible material.
Clean-Up Procedures: Collect spilled material in sealable containers for disposal. Wash contaminated area with detergent and water.
Handling: Avoid inhalation, ingestion, and skin or eye contact. Use with adequate ventilation. Keep containers tightly sealed.
Storage: Store in cool, dry, well-ventilated area. Protect from sunlight and incompatible materials such as oxidizing agents. Temperature range: 5–30°C (41–86°F).
Incompatibilities: Strong acids, oxidizers, reducing agents, and polymerization initiators.
Occupational Exposure Limits: No specific OEL set for this compound. Follow good industrial hygiene practices.
Engineering Controls: Local exhaust, eyewash stations, emergency shower in area.
Personal Protective Equipment: Chemical-resistant gloves (nitrile), safety goggles, long-sleeved clothing, respiratory protection (NIOSH-approved if limits are exceeded).
Hygiene Measures: Wash hands before breaks and after handling. Do not eat, drink, or smoke during use.
Appearance: Clear, colorless liquid
Odor: Faint ester-like
Boiling Point: 220°C (428°F)
Melting Point: -60°C (-76°F)
Flash Point: 110°C (230°F) Closed Cup
Density: 1.13 g/cm³
Solubility: Slightly soluble in water, miscible with most organic solvents
Vapor Pressure: 0.001 hPa at 20°C
Viscosity: 8.2 mPa·s at 20°C
pH: Not applicable (neutral substance)
Partition Coefficient (log Kow): 1.02
Chemical Stability: Stable under recommended storage conditions
Reactivity: No hazardous reactions if used as directed
Possibility of Hazardous Reactions: Exothermic polymerization possible in contact with heat, light, peroxides, or radical initiators
Conditions to Avoid: Overheating, exposure to sunlight, strong oxidizers or acids
Incompatible Materials: Strong oxidants, reducing agents, peroxides
Hazardous Decomposition Products: Methacrylic acid fumes, carbon monoxide, carbon dioxide
Acute Toxicity: Oral LD50 (rat): 4000 mg/kg
Skin Corrosion/Irritation: Causes irritation in humans and laboratory animals
Serious Eye Damage/Irritation: Causes irritation, redness, watering
Respiratory or Skin Sensitization: Sensitization possible with repeated contact
Germ Cell Mutagenicity: Not classified
Carcinogenicity: No data suggest carcinogenic effects
Reproductive Toxicity: No indication from available studies
Repeated Dose Toxicity: Prolonged exposure may cause dermatitis, respiratory irritation
Ecotoxicity: Aquatic toxicity low with LC50 (fish, 96h): 45 mg/L
Persistence and Degradability: Readily biodegradable based on OECD 301D test
Bioaccumulative Potential: Log Kow low, low potential
Mobility in Soil: Mobile in water, may leach
Other Adverse Effects: No known indirect environmental impacts
Waste Treatment Methods: Incineration or disposal in accordance with local, regional, national, and international regulations
Container Disposal: Triple rinse and puncture containers before disposal. Do not reuse empty containers.
Precautions: Do not discharge to natural waters or sewer system
UN Number: Not regulated for transport
Proper Shipping Name: Not classified as dangerous goods
Transport Hazard Class: None assigned
Packing Group: None
Environmental Hazards: Not a marine pollutant
Special Precautions for User: Avoid release to environment during transport. Prevent leaks with proper packaging.
TSCA: Listed in inventory
REACH: Pre-registered and compliant
OSHA: Hazardous by definition, as per 29 CFR 1910.1200
WHMIS (Canada): Class D2B (irritant)
Inventory Listings: KECL (Korea), EINECS/ELINCS (EU), AICS (Australia), DSL/NDSL (Canada)
Other Regulations: Observe workplace exposure limits and use recommended PPE as required under jurisdictional law
