Ascent Petrochem Holdings Co., Limited

Knowledge

MSDS of Bio-Isobornyl Methacrylate

Identification

Product Name: Bio-Isobornyl Methacrylate
Chemical Formula: C14H22O2
Synonyms: BIBOMA, Isobornyl Methacrylate (bio-based)
CAS Number: 7534-94-3
Recommended Use: Polymer and resin synthesis, adhesives, coatings
Supplier: Contact information of the manufacturer or distributor, including address and emergency phone number

Hazard Identification

GHS Classification: Flammable liquid (Category 3), Skin irritation (Category 2), Eye irritation (Category 2A), Sensitization (Category 1)
Signal Word: Warning
Hazard Statements: Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Flammable liquid and vapor.
Pictograms: Flame, Exclamation Mark
Precautionary Statements: Avoid breathing dust or vapors. Keep away from heat, sparks, open flames. Wear protective gloves, protective clothing, and eye protection.

Composition / Information on Ingredients

Chemical Name: Isobornyl Methacrylate
Common Name: Bio-Isobornyl Methacrylate
CAS Number: 7534-94-3
Concentration: ≥99%
Impurities/Additives: Trace stabilizers (Methoxyphenol, MEHQ)

First Aid Measures

Inhalation: Move person to fresh air. Seek medical attention if symptoms persist.
Skin Contact: Remove contaminated clothing. Rinse skin with water and seek medical advice for irritation.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present. Continue rinsing and get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting. Call a doctor or Poison Center right away.
Symptoms: Irritation, redness, itching, difficulty breathing in severe cases.

Fire-Fighting Measures

Suitable Extinguishing Media: Dry powder, alcohol-resistant foam, carbon dioxide, water spray
Specific Hazards: Flammable vapors. Containers may burst when heated. Potential for explosive vapor-air mixtures.
Special Protective Equipment: Firefighters wear self-contained breathing apparatus and full protective clothing.
Hazardous Combustion Products: Carbon oxides, acrid smoke, other toxic fumes.

Accidental Release Measures

Personal Precautions: Keep away from ignition sources. Ventilate area. Use personal protective equipment.
Environmental Precautions: Prevent spill from entering drains and waterways.
Cleanup Methods: Absorb leak with inert material (sand, earth). Place in properly labeled, closed container for disposal. Clean area with detergent and water.
Reporting: Inform authorities as required by local, state, and federal regulations.

Handling and Storage

Handling: Keep away from open flame and heat. Ground equipment to prevent static discharge. Use only in well-ventilated areas. Avoid contact with skin, eyes, and clothing.
Storage: Keep in a tightly-sealed, original container in a cool, dry, well-ventilated location. Store away from oxidizers and sunlight. Protect from freezing. Keep separate from food and drink.

Exposure Controls and Personal Protection

Occupational Exposure Limit: No specific exposure limit established. Recommend keeping below 10 ppm for extended tasks.
Engineering Controls: Use local exhaust ventilation, fume hoods.
Personal Protection: Chemical-resistant gloves (nitrile), goggles or face shield, flame retardant protective clothing, and in some circumstances, an organic vapor respirator.
Hygiene Measures: Wash hands after use. Remove contaminated clothing and clean before reuse. No eating, drinking, or smoking near work area.

Physical and Chemical Properties

Appearance: Clear, colorless to slightly yellow liquid
Odor: Characteristic mild, camphor-like smell
Boiling Point: 245°C (473°F)
Melting Point: -60°C (-76°F)
Flash Point: 98°C (208°F) (closed cup)
Vapor Pressure: 0.15 mmHg at 20°C
Density: 0.97 g/cm³ at 20°C
Solubility: Insoluble in water, miscible with organic solvents
Viscosity: 7-9 mPa.s at 23°C
pH: Not applicable
Partition Coefficient (log Pow): 4.1
Evaporation Rate: Slow, compared to water

Stability and Reactivity

Chemical Stability: Stable under recommended handling and storage.
Polymerization Risk: Polymerization can release heat. Inhibitors (MEHQ) required in container.
Incompatible Materials: Strong oxidizing agents, strong acids/bases, free radical initiators
Conditions to Avoid: Heat, light, sparks, high temperature
Hazardous Decomposition: Carbon monoxide, carbon dioxide, smoke, potential acrylate fumes.

Toxicological Information

Acute Toxicity: Oral LD50 (rat) > 5000 mg/kg
Skin Corrosion/Irritation: Repeated or prolonged contact causes irritation
Serious Eye Damage/Irritation: Causes moderate to severe irritation
Respiratory Sensitization: May cause respiratory irritation
Skin Sensitization: Possible allergenic reactions (dermatitis)
Mutagenicity: No evidence in standard tests
Carcinogenicity: Not classified as carcinogenic
Chronic Effects: Long-term exposure aggravates eczema and skin allergies.

Ecological Information

Ecotoxicity: Harmful to aquatic organisms
Aquatic Toxicity: LC50 (Fish, 96 h) > 10 mg/L
Persistence and Degradability: Partially biodegradable
Bioaccumulation: Potential for bioaccumulation based on log Pow 4.1
Mobility in Soil: Low mobility, hydrophobic
Other Adverse Effects: No known significant effects outside aquatic environments

Disposal Considerations

Disposal Methods: Dispose contents/container in accordance with local, state, and federal regulations. Send to licensed waste treatment site.
Packaging: Decontaminate container by triple rinsing and puncture before recycling or disposal.
Handling Waste: Prevent releases to the environment. Never pour into drains or sewers.
Contaminated Packaging: Treat as hazardous waste.

Transport Information

UN Number: UN 1993
Proper Shipping Name: Flammable Liquid, N.O.S. (contains Isobornyl Methacrylate)
Transport Hazard Class: 3(flammable liquids)
Packing Group: III
Environmental Hazards: Not a marine pollutant
Special Precautions: Ensure containers remain upright and secure during transit.

Regulatory Information

Labelling Requirements: Complies with OSHA Hazard Communication Standard (29 CFR 1910.1200)
US TSCA: Listed
EU REACH: Registered or pre-registered
SARA 313 (US): Not listed
California Proposition 65: This chemical is not listed as a carcinogen or reproductive toxin.
Other Local Regulations: Observe country, state, and local environmental and safety regulations.