Product Name: 2-Phenoxyethyl Methacrylate
Synonyms: Methacrylic acid 2-phenoxyethyl ester
CAS Number: 10595-06-9
Recommended Use: Polymer resin, industrial chemical, coatings, adhesives
Supplier: Chemical manufacturer or distributor address and contact
Emergency Contact: Check local and national poison control centers
GHS Classification: Skin Irritation (Category 2), Eye Irritation (Category 2A), Sensitization (Category 1), Environmental Hazard (Aquatic Chronic Category 3)
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, may cause allergic skin reaction, harmful to aquatic life with long-lasting effects
Pictograms: Exclamation mark, Environment
Precautionary Statements: Avoid skin and eye contact, use protective equipment, prevent environmental release, wash thoroughly after handling
Chemical Name: 2-Phenoxyethyl Methacrylate
CAS Number: 10595-06-9
Concentration: >99%
Impurities: Trace amounts of methyl methacrylate, phenol derivatives
Molecular Formula: C12H14O3
Molecular Weight: 206.24 g/mol
Eye Contact: Flush eyes gently with plenty of clean water for at least 15 minutes, hold eyelids open, seek immediate medical attention
Skin Contact: Remove contaminated clothing, wash exposed skin with soap and water, seek medical help if irritation develops
Inhalation: Move person to fresh air, keep warm and at rest, get medical attention if symptoms occur
Ingestion: Rinse mouth thoroughly, never induce vomiting, get medical advice
Notes for Physicians: No specific antidote; treat symptomatically and supportively
Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, foam, water spray (do not use direct water jet on burning liquid)
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, smoke, irritating fumes
Firefighting Instructions: Wear self-contained breathing apparatus and full protective suit
Special Hazards: Flammable vapors may travel along ground to distant ignition points, containers may explode under fire conditions
Additional Recommendations: Cool exposed containers using water spray, prevent firefighting water from entering drains
Personal Precautions: Evacuate unnecessary personnel, ventilate area, wear protective gear including chemical splash goggles, gloves, and suitable respirator
Environmental Precautions: Avoid discharge to surface water, soil, drains
Cleanup Methods: Absorb spill with inert material (sand, earth), collect in suitable containers for disposal, wash contaminated area with water and detergent
Additional Guidance: Use spark-proof tools, remove ignition sources, prevent vapor buildup
Handling: Use only in well-ventilated areas, avoid inhaling fumes or vapor, prevent skin and eye contact, ground containers during transfer
Storage: Store in tightly closed, original container, away from heat, sparks, open flame, and incompatible materials (acids, oxidizers, bases)
Storage Temperature: Maintain below 25°C away from direct sunlight
Other Information: Keep away from food, drink and animal feed, avoid prolonged storage, handle using good industrial hygiene
Occupational Exposure Limits: No established workplace exposure limits; minimize exposure as much as possible
Engineering Controls: Local exhaust, general ventilation, fume hoods
Personal Protection: Chemical-resistant gloves (nitrile or neoprene), safety spectacles or full-face shield, protective clothing, suitable respiratory protection if airborne concentration exceeds control parameters
Hygiene Measures: No eating, drinking or smoking during use, wash hands and face thoroughly after handling
Monitoring: Regular workplace air monitoring for methacrylate vapors
Appearance: Colorless to pale yellow liquid
Odor: Faint, aromatic
Odor Threshold: Not available
pH: Not applicable (non-aqueous)
Melting Point: -35°C
Boiling Point: 270°C
Flash Point: 115°C (closed cup)
Evaporation Rate: Not available
Flammability: Combustible
Vapor Pressure: <0.1 mmHg at 20°C
Vapor Density: Heavier than air
Relative Density: 1.09 – 1.11 g/cm³
Solubility: Slightly soluble in water, soluble in most organic solvents
Partition Coefficient (log Kow): 2.5 – 3
Auto-ignition Temperature: 320°C
Decomposition Temperature: Not established
Viscosity: 3-6 mPa.s at 25°C
Chemical Stability: Stable at recommended storage conditions
Polymerization: May occur if exposed to heat, light, free-radical initiators (inhibitor usually added to prevent polymerization)
Conditions to Avoid: High temperatures, direct sunlight, sources of ignition, incompatible substances
Incompatible Materials: Strong oxidizing agents, strong acids, strong bases, peroxides
Hazardous Decomposition Products: Methacrylic acid, phenol, carbon oxides, irritating vapors
Protective Measures: Store with stabilizer present, avoid uncontrolled mixing
Acute Toxicity: Oral LD50 (rat): 4000 mg/kg; skin LD50 (rabbit): 2000 mg/kg (estimated)
Skin Corrosion/Irritation: Moderately irritating
Serious Eye Damage/Irritation: May cause eye irritation
Respiratory/Skin Sensitization: May cause allergic reactions on contact
Germ Cell Mutagenicity: Not classified; inadequate data
Carcinogenicity: Not listed as a carcinogen by IARC, NTP, OSHA
Reproductive Toxicity: No evidence from available studies
Specific Target Organ Toxicity: Prolonged inhalation may affect central nervous system
Aspiration Hazard: Not classified as hazard for aspiration
Other Effects: May cause nausea, dizziness, headaches at high concentrations
Aquatic Toxicity: Harmful to aquatic organisms, LC50 (fish, 96h): >10 mg/L
Invertebrate Toxicity: EC50 (daphnia, 48h): >10 mg/L
Degradability: Readily biodegradable in standard tests
Bioaccumulation Potential: Moderate, log Kow between 2.5 and 3
Mobility in Soil: Low to moderate, slight water solubility and high absorption capacity
Other Adverse Effects: Product contains no substances known to cause long-term environmental harm beyond listed hazards
Disposal Methods: Incinerate under controlled conditions or dispose at approved chemical waste facility following local, regional, and national regulations
Avoid Disposal Into: Sewer systems, surface waters, trash or household waste
Container Disposal: Empty containers must be triple-rinsed, punctured or crushed before disposal, follow label instructions
Waste Code: Check local or national hazardous waste numbers for methacrylate products
Additional Notes: Recycle or reclaim solvent whenever possible to minimize impact
UN Number: 3082 (environmentally hazardous substance, liquid, N.O.S.)
UN Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (2-Phenoxyethyl Methacrylate)
Transport Hazard Class(es): 9
Packing Group: III
Labels: Miscellaneous Dangerous Goods, Environmentally Hazardous
Special Precautions: Protect containers from damage and leaking, avoid mixed loads with foodstuffs or oxidizers
OSHA: Not specifically regulated under 29 CFR 1910.1000
TSCA: Listed in United States TSCA inventory
EINECS/ELINCS: Listed as 234-238-5
REACH: Not subject to restriction; may require registration for use in European Union
SARA Title III: Not listed under Section 313
Other Regulations: Follow all state, local, and federal guidelines for methacrylates and hazardous chemicals
Labeling: Ensure all containers and work areas display appropriate warnings and hazard information
