Product Name: 2-(2'-Vinyloxyethoxy)Ethyl Acrylate
Synonyms: VEEA, Acrylate monomer, Vinyloxyethyl acrylate
Chemical Formula: C9H14O4
CAS Number: 86272-85-5
Manufacturer Details: [Insert Manufacturer’s Name and Address]
Recommended Use: Used in coatings, adhesives, and polymer synthesis
Restrictions on Use: Not approved for food packaging or medical applications
Emergency Contact: [Insert 24-hour Emergency Telephone Number]
GHS Classification: Flammable Liquid, Category 3; Skin Irritant, Category 2; Eye Irritant, Category 2A; Skin Sensitizer, Category 1; Acute Toxicity (Oral), Category 4
Signal Word: Warning
Hazard Statements: Flammable liquid and vapor; Causes skin and eye irritation; May cause an allergic skin reaction; Harmful if swallowed
Precautionary Statements: Keep away from heat, sparks, open flames; Avoid breathing vapor or mist; Wear protective gloves, clothing, and eye protection; Use only outdoors or in a well-ventilated area; Wash thoroughly after handling
Pictograms: Flame, Exclamation Mark
Other Hazards: Can form explosive mixtures with air; Polymerization may occur under uncontrolled conditions
Chemical Name: 2-(2'-Vinyloxyethoxy)Ethyl Acrylate
Chemical Formula: C9H14O4
CAS Number: 86272-85-5
Concentration: >98% (by weight)
Impurities: Trace inhibitors (e.g., phenothiazine, hydroquinone at <0.1%)
Additives: None unless otherwise stated by supplier
Inhalation: Move person to fresh air. Seek immediate medical attention if breathing becomes difficult or if symptoms persist.
Skin Contact: Remove contaminated clothing. Rinse skin with plenty of water for at least 15 minutes. Use soap if available. Seek medical advice if irritation develops.
Eye Contact: Rinse eyes cautiously with water for several minutes, removing contact lenses if present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion: Do not induce vomiting. Rinse mouth thoroughly. If conscious, provide water to drink. Get medical help.
Most Important Symptoms/Effects: Redness, pain, sensitization, potential chemical burns, respiratory distress
Immediate Medical Attention Needed: Yes, especially for eye or inhalation exposure
Suitable Extinguishing Media: Alcohol-resistant foam, carbon dioxide (CO2), dry chemical, water spray
Unsuitable Extinguishing Media: Do not use high pressure direct water jets
Specific Hazards: Vapors may travel along surfaces and ignite at distant sources; Forms hazardous decomposition products such as carbon oxides, acrylate fumes
Protective Actions: Move containers from fire area if it can be done safely; Use water spray to cool fire-exposed containers
Protective Equipment: Self-contained breathing apparatus (SCBA) and full protective gear required
Fire/Explosion Risks: May form flammable/explosive vapor-air mixture; Polymerization by fire heat can cause pressure buildup
Personal Precautions: Evacuate unnecessary personnel; Use suitable personal protective equipment; Remove sources of ignition, ventilate area
Environmental Precautions: Prevent spillage from entering drains, sewers, water courses
Containment / Cleanup: Absorb spilled liquid with inert material (sand, earth, vermiculite). Collect in suitable, closed containers for disposal. Use non-sparking tools.
Decontamination Methods: Wash contaminated area thoroughly with water and detergent; Dispose of cleaning materials as hazardous waste
Reporting: Notify local authorities if release has caused environmental contamination
Handling: Work only in well-ventilated locations; Avoid contact with skin, eyes, and clothing; Do not breathe vapor; Keep away from sources of ignition and static discharge
General Hygiene: No eating, drinking, or smoking during use. Wash hands and face before eating or after handling.
Storage: Store in cool, dry, well-ventilated facility in tightly closed original container; Protect from sunlight, moisture, and heat sources
Incompatibilities: Avoid strong oxidizers, strong acids, bases, and amines; Keep separate from food and feedstuffs
Technical Measures: Ground containers when transferring material; Store with stabilizer/inhibitor as recommended
Control Parameters: No established occupational exposure limits; Use threshold limit values for similar acrylates as guidelines
Engineering Controls: Use local exhaust ventilation or process enclosure to minimize vapor exposure
Respiratory Protection: Use organic vapor respirator if ventilation insufficient
Hand Protection: Nitrile rubber or butyl gloves recommended
Eye Protection: Chemical splash goggles
Skin and Body Protection: Wear long sleeves, chemical-resistant apron, and closed-toe shoes
Additional Measures: Emergency eyewash and safety shower stations nearby
Appearance: Clear, colorless to pale yellow liquid
Odor: Acrylate-like, mild
Odor Threshold: Not established
pH: Not applicable (non-aqueous)
Melting Point/Freezing Point: Below -20°C
Boiling Point/Range: 100–120°C at 760 mm Hg (approximate)
Flash Point: 72–80°C (closed cup)
Evaporation Rate: Not determined
Flammability: Flammable liquid
Explosive Limits: Not available
Vapor Pressure: 0.3–0.8 mm Hg at 25°C
Vapor Density: Heavier than air
Relative Density: 1.08–1.12 g/cm³ at 20°C
Solubility in Water: Slightly soluble
Solubility in Solvents: Miscible with most common organic solvents
Partition Coefficient n-octanol/water: Log Pow >2 (estimated)
Auto-ignition Temperature: Not determined
Decomposition Temperature: Above 180°C
Viscosity: 8–18 mPa•s at 25°C
Chemical Stability: Stable under recommended handling and storage conditions
Conditions to Avoid: Heat, open flame, spark, direct sunlight, static discharge
Polymerization: Risk of uncontrolled polymerization at high temperature or in the absence of inhibitor
Incompatible Materials: Strong acids, bases, oxidizers, amines, peroxides
Hazardous Decomposition Products: Acrylate fumes, carbon monoxide, carbon dioxide, organic vapors
Acute Toxicity: Estimated oral LD50 (rat) 300–2000 mg/kg
Skin Effects: Can cause moderate to severe irritation; May cause sensitization on repeated exposure
Eye Effects: Severe irritation, possible corneal injury
Inhalation: Vapor inhalation can cause respiratory tract irritation, headache, dizziness
Chronic Effects: Repeated exposure can amplify allergic response and skin sensitization
Other Data: No evidence of carcinogenicity or mutagenicity in available studies; Long-term data insufficient for full chronic risk profile
Toxicity to Aquatic Life: Harmful to aquatic organisms with long-lasting effects; LC50 (fish, 96h) estimated 10–100 mg/L
Persistence and Degradability: Some biodegradation expected, not readily degradable
Bioaccumulation Potential: Moderate due to hydrophobic nature
Mobility in Soil: Potential to leach to groundwater if released
Other Adverse Effects: Not classified as ozone depleting; Minimize environmental contamination
Waste Handling Methods: Dispose of content in accordance with local, regional, and national regulations as hazardous chemical waste
Container Disposal: Triple rinse and destroy by crushing or incineration under controlled conditions
Precautions: Do not release into drains or water bodies; Avoid uncontrolled incineration or landfill dumping
Recommended Disposal: Use licensed chemical waste contractor; Handle wash solutions as hazardous waste
UN Number: UN 1993
Proper Shipping Name: Flammable Liquid, N.O.S. (contains 2-(2'-Vinyloxyethoxy)Ethyl Acrylate)
Transport Hazard Class: 3 (Flammable liquid)
Packing Group: III
Label(s) Required: Flammable Liquid
Marine Pollutant: Yes
Special Transport Precautions: Store upright; Prevent package rupture; Avoid temperature extremes during transport
Safety, Health and Environmental Regulations: Product subject to workplace chemical regulations such as OSHA Hazard Communication Standard (USA), REACH (Europe), WHMIS (Canada) and equivalent local programs
SARA Title III (Sections 311/312): Fire hazard, Acute health hazard
TSCA Inventory: Listed or may require reporting
Signal Word According to GHS: Warning
EU Classification: Xi (Irritant), R36/37/38, R43, F (Flammable)
Restrictions: Not approved for direct food, pharmaceutical, or cosmetic uses
Other Regulatory Listings: Confirm with national inventories before importing or exporting
